174. Electricity in motion is transmuted into _heat_ during the passage
of a current along a thin wire, or any badly conducting substance--the
wire is heated in consequence, and may even become white hot. Most
frequently the energy of an electric current is spent in heating the
wires and other materials that form the circuit. Now, the energy
of such a current is fed by the burning or oxidation of the metal
(generally zinc) which is used in the circuit, so that the ultimate
effect of this combustion is the heating of the various wires and other
materials through which the current passes.
175. We may, in truth, burn or oxidize zinc in two ways--we may oxidize
it, as we have just seen, in the voltaic battery, and we shall find
that by the combustion of a kilogramme of zinc a definite amount of
heat is produced. Or we may oxidize our zinc by dissolving it in acid
in a single vessel, when, without going through the intermediate
process of a current, we shall get just as much heat out of a
kilogramme of zinc as we did in the former case. In fact, whether we
oxidize our zinc by the battery, or in the ordinary way, the quantity
of heat produced will always bear the same relation to the quantity of
zinc consumed; the only difference being that, in the ordinary way of
oxidizing zinc, the heat is generated in the vessel containing the zinc
and acid, while in the battery it may make its appearance a thousand
miles away, if we have a sufficiently long wire to convey our current.
176. This is, perhaps, the right place for alluding to a discovery
of Peltier, that a current of positive electricity passing across a
junction of bismuth and antimony in the direction from the bismuth to
the antimony appears to produce cold.
[Illustration: Fig. 14.]
To understand the significance of this fact we must consider it in
connection with the thermo-electric current, which we have seen, from
Art. 161, is established in a circuit of bismuth and antimony, of
which one junction is hotter than the other. Suppose we have a circuit
of this kind with both its junctions at the temperature of 100° C.
to begin with. Suppose, next, that while we protect one junction, we
expose the other to the open air--it will, of course, lose heat, so
that the protected junction will now be hotter than the other. The
consequence will be (Art. 161) that a current of positive electricity
will pass along the protected junction from the bismuth to the
antimony.
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