Similar laws apply to all light gases which do not turn into fluids or
solids at low temperatures. Aqueous vapour, on the other hand, which
when cooled condenses to clouds, diminishes much faster than the nearly
twice as heavy oxygen, because the temperature rapidly decreases as we
move upward or at a rate of about 5° C. per km. (14.5° F. per mile)
up to 2.5 km. (1.5 miles) and of 8° C. per km. (23° F. per mile) at a
height of 8.5 km. (5.3 miles). The quantity of water vapour shrinks to
one half at 1.9 km. (slightly more than a mile) above ground. Carbon
dioxide again follows the barometer-formula applicable to other gases
because it occurs in such minute quantity that it never condenses to
clouds. In fact, it is water vapour alone which must be treated as an
exception. Carbon dioxide is nearly one and one half times heavier than
the other gases of the atmosphere on an average. It should therefore
diminish in the proportion 1:2^{1.5} = 1:2.8 in a vertical distance of
5 km. (3.1 miles) while the density of the air decreases only in the
ratio 1:2. Several determinations of the presence of carbon dioxide
in the atmosphere as high up as 3.8 km. (2.33 miles) have been made,
by S. A. Andree among others, but the percentage of this gas remains
constant within the errors of observation. The same holds true to a
height of 7 km. (4.35 miles) for the proportion between oxygen and
nitrogen, although we might have expected a perceptible change as
oxygen is 14 per cent. heavier than nitrogen. How shall we explain this
fact which seemingly contradicts the theory just advanced?
The explanation is quite simple. The preceding statements hold true for
a mass of air at perfect rest. But, if the air is violently agitated,
the composition becomes homogeneous all through. We know that in the
barometric cyclones and anticyclones strong rising and descending air
currents flow. The composition of the atmosphere, therefore, becomes
the same as far up as this mixing action prevails. These currents
produce another effect, namely, a fall of temperature with rising
height. Because when a gas is transported upward the surrounding
pressure decreases, resulting in expansion and consequent cooling. It
is well known that a gas is heated when (rapidly) compressed, a quality
formerly made use of in the pneumatic fire-tool to ignite tinder. It is
evident that conversely a gas must cool off when expanding. If now the
mixing of the air were extremely rapid the thermometer would fall very
close to 10° C. (18° F.) with each km. (.62 miles) rise in elevation.
If, on the other hand, the air stood perfectly still in a vertical
direction, the temperature would remain constant at all heights
over the same point. Between these two extremes, we find the actual
condition, inasmuch as the temperature of the atmosphere decreases
upward 5° to 8° C. per km. (14.5° to 23° F. per mile) as observed
during balloon ascensions.
Public-domain text, read in full here on John Shaqi.
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