The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and StudentBeech, Franklin
Science
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student
Beech, Franklin
Dyes and dyeing -- Cotton
To give tables showing the effects of these reagents on the numerous
dyes now known would take up too much room and not serve a very useful
purpose, as such tables, if too much relied on, leave the operator
somewhat uncertain as to what he has before him. The reader will find in
Hurst's _Dictionary of Coal-tar Colours_ some useful notes as to the
action of acids and alkalies on the various colours that may be of
service to him.
Alizarine and the series of dye-stuffs to which it has given its name,
fustic, cochineal, logwood and other dyes of a similar class require the
fabric to be mordanted, and the presence of such mordant is occasionally
an indirect proof of the presence of these dyes.
To detect these mordants, a piece of the swatch should be burnt in a
porcelain or platinum crucible over a Bunsen burner, care being taken
that all carbonaceous matter be burnt off. A white ash will indicate the
presence of alumina mordants, red ash that of iron mordants, and a
greenish ash chrome mordants.
To confirm these the following chemical tests may be applied: Boil the
ash left in the crucible with a little strong hydrochloric acid and
dilute with water. Pass a current of sulphuretted hydrogen gas through
the solution; if there be any tin present a brown precipitate of tin
sulphide will be obtained. This can be filtered off. The filtrate is
boiled for a short time with nitric acid, and ammonia is added to the
solution when alumina is thrown down as a white gelatinous precipitate;
iron is thrown down as a brown red bulky precipitate; while chrome is
thrown down as a greyish-looking gelatinous precipitate. The precipitate
obtained with the ammonia is filtered off, and a drop of ammonium
sulphide added, when any zinc present will be thrown down as white
precipitate of zinc sulphide: to the filtrate from this ammonium oxalate
may be added, when if lime is present a white precipitate of calcium
oxalate is obtained.
A test for iron is to dissolve some of the ash in a little hydrochloric
acid, and add a few drops of potassium ferrocyanide solution, when if
any iron be present a blue precipitate will be obtained.
To make more certain of the presence of chrome, heat a little of the ash
of the cloth with caustic soda and chlorate of soda in a porcelain
crucible until well fused, then dissolve in water, acidify with acetic
acid and add lead acetate; a yellow precipitate indicates the presence
of chrome.
A book on qualitative chemical analysis should be referred to for
further details and tests for metallic mordants.
Public-domain text, read in full here on John Shaqi.
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