Alkaline or soap baths do not work well as a rule, and must be avoided
in wool dyeing. Generally the dye-bath is exhausted of colour, and
full shades are easily obtained, while these reds are in general
remarkable for the evenness and uniformity of tint which can be (p. 101)
produced. The reds so dyed are, on the whole, fairly fast to soaping,
and can be used for dyeing goods that have to be milled, while their
resistance to light and air is fairly good. Benzopurpurine and Diamine
Red are more or less affected by acids, but the Titan Red and some of
the more modern reds, Diamine Brilliant Scarlet, Benzo Fast Scarlets,
are all fast to acids. The fastness to washing and light of some of
them, Benzo Fast Red, Diamine Fast Red F, Titan Red, is much increased
by adding, after the wool has been dyed, 3 per cent. of fluoride of
chromium to the dye-bath, and working a little longer.
The dyeing with these colours is done at the boil, and the goods may
be entered direct into the boiling bath without fear of uneven shades
being produced. This bath may be kept as a standing one, simply adding
as each lot is dyed the necessary quantity of dye-stuff, a little
fresh water to bring the bath up to its original volume, and a
corresponding quantity of the salt originally added. The wool can then
be entered and dyed.
In place of using salt or Glauber's salt, acetate of ammonia is an
excellent assistant for this class of dyes.
The following are some recipes for dyeing various shades of red on
wool with this class of dyes.
_Scarlet_.--The dye-bath is made with 3 lb. Titan Scarlet C B, and
10 lb. acetate of ammonia. This gives a good bright shade of scarlet,
which is fast to acids and soaping, although not fast to light.
_Scarlet_.--Dye in a bath made with 3 lb. Diamine Scarlet B and 10 lb.
Glauber's salt. This yields a light shade, not so fast to acids as the
last, but equally fast to soaping and light.
_Scarlet_.--Make the dye-bath with 3 lb. Benzopurpurine 4 B, and
10 lb. Glauber's salt. This also gives a good shade of Scarlet fast to
soaping. It is turned dark blue by acids, and is not fast to (p. 102)
light. It is very largely used on underwear goods, but is not so
satisfactory for this as the Titan Scarlet C B, or Benzo Fast
Scarlet B S.
_Scarlet_.--The dye-bath may be made with 3 lb. Brilliant Congo G,
10 lb. Glauber's salt and 2 lb. acetate of ammonia. This gives a
satisfactory shade of scarlet.
_Bright Scarlet_.--The dye-bath prepared with 2 lb. Geranine G, 5 lb.
sulphate of soda, 5 lb. acetate of ammonia. Work at the boil for one
hour, then wash and dry.
_Dark Crimson_.--Prepare a dye-bath with 1-1/2 lb. Chrysophenine,
1-1/2 lb. Hessian Violet, 25 lb. salt. Heat to 150 deg. F., enter the
goods, heat to boil and dye boiling for one hour, take out, rinse and
wash.
_Scarlet_.--A brilliant shade of scarlet can be dyed in a bath of
3 lb. Benzo Fast Red, 1 lb. Chrysophenine, 10 lb. Glauber's salt and
2 lb. acetic acid.
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