The Economic Aspect of GeologyLeith, C. K. (Charles Kenneth)
Science
The Economic Aspect of Geology
Leith, C. K. (Charles Kenneth)
Geology, Economic
Before the war domestic sources supplied a fourth to a third of the
domestic demand for pyrite. Imports came mainly from Spain and Portugal
to consuming centers on the Atlantic seaboard. The curtailment of
overseas imports of pyrite during the war increased domestic production
by about a third and resulted also in drawing more heavily on Canadian
supplies, but the total was not sufficient to meet the demand. The
demand was met by the increased use of sulphur from domestic deposits
(p. 109). At the close of the war supplies of pyrite had been
accumulated to such an extent that, with the prospect of reopening of
Spanish importation, pyrite production in the United States practically
ceased. War experience has demonstrated the possibility of substitution
of sulphur, which the United States has in large and cheaply mined
quantities. The future of the pyrite industry in the United States
therefore looks cloudy, except for supplies used locally, as in the
territory tributary to the Great Lakes, and except for small amounts
locally recovered as by-products in the mining of coal or from ores of
zinc, lead, and copper. Pyrite production in the past has been chiefly
in the Appalachian region, particularly in Virginia and New York, and in
California.
GEOLOGIC FEATURES
Pyrite, the yellow iron sulphide, is the commonest and most abundant of
the metallic sulphides. It is formed under a large variety of conditions
and associations. Marcasite and pyrrhotite, other iron sulphide
minerals, are frequently found with pyrite and are used for the same
purposes.
The great deposits of Rio Tinto, Spain, which produce about half of the
world's pyrite, were formed by replacement of slates by heated solutions
from nearby igneous rocks. The ores are in lenticular bodies, and
consist of almost massive pyrite with a small amount of quartz and
scattered grains and threads of chalcopyrite (copper-iron sulphide).
They carry about 50 per cent of sulphur, and the larger part carries
about 2 per cent of copper which is also recovered.
Similar occurrences of pyrite on a smaller scale are known in many
places. Pyrite is very commonly found in vein and replacement deposits
of gold, silver, copper, lead, and zinc. In the Mississippi valley it is
extracted as a by-product from the lead and zinc ores, and in the
Cordilleran region large quantities of by-product pyrite could easily be
produced if there were a local demand. The pyrite deposits of the
Appalachian region are chiefly lenses in schists; they are of uncertain
origin though some are believed to have been formed by replacement of
metamorphosed limestones and schists.
Under weathering conditions pyrite oxidizes, the sulphur forming
sulphuric acid,--an important agent in the secondary enrichment of
copper and other sulphides,--and the iron forming the minerals hematite
and limonite in the shape of a "gossan" or "iron-cap."
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