The Economic Aspect of GeologyLeith, C. K. (Charles Kenneth)
Science
The Economic Aspect of Geology
Leith, C. K. (Charles Kenneth)
Geology, Economic
The antimony sulphide, stibnite, is the source of most of the world's
production of this metal. Antimony oxides, including senarmontite,
cervantite, and others, are formed near the surface, and in some of the
deposits of Mexico and Algeria they supply a large part of the values
recovered. Jamesonite, bournonite, and tetrahedrite (sulphantimonides of
lead and copper), when found in lead-silver deposits, are to some extent
a source of antimony in the form of antimonial lead.
Stibnite is found in a variety of associations and is present in small
quantities in many types of deposits. In the commercial antimony
deposits, it is in most cases accompanied by minor quantities of other
metallic sulphides--pyrite, cinnabar, sphalerite, galena, arsenopyrite,
etc.--in a gangue of quartz and sometimes calcite. Many of the deposits
contain recoverable amounts of gold and silver.
The deposits of the Hunan Province of southern China occur as seams,
pockets, and bunches of stibnite ore in gently undulating beds of
faulted and fissured dolomitic limestone. In the vicinity of the most
important mines no igneous rocks have been observed, and the origin of
the ores has not been worked out.
In the Central Plateau of France the numerous antimony deposits are
stibnite veins cutting granites and the surrounding schists and
sediments. An origin related in some way to hot ascending solutions
seems probable.
The deposits of the National district of western Nevada, the most
important war-developed antimony deposits of the United States, consist
of stibnite veins with a gangue of fine-grained drusy quartz, cutting
through flows of rhyolite and basalt. They are intimately related to
certain gold- and silver-bearing veins, and all are closely associated
with dikes of rhyolite, which were the feeders to the latest extrusion
in the district. The wall rocks have undergone alteration of the
propylitic type. These relations, and the presence of the mercury
sulphide, cinnabar, in some of the ores (see pp. 258-259), suggest an
origin through the work of ascending hot waters or hot springs. These
waters probably derived their dissolved matter from a magmatic source,
and worked up along vents near the rhyolite dikes soon after the
eruption of this rock.
In the weathering of antimony deposits, the stibnite usually alters to
form insoluble white or yellowish oxides, which are sometimes called
"antimony ocher." These tend to accumulate in the oxide zone through the
removal of the more soluble accompanying minerals. Secondary sulphide
enrichment of antimony deposits, if it occurs at all, is negligible.
ARSENIC ORES
ECONOMIC FEATURES
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