The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
[H^{+}]×[HO^{−}] at 25° 1.2E−14
at 100° 0.5E−11
TABLE NOTES:
A. As explained on p. 100, the bracketed values given for
the strong acids ‹are not constants›, but express the values
of the ratios [H^{+}] × [Anion] / [Acid] for 0.1 ‹molar
solutions›.
B. See references, Noyes, ‹ibid.›, «32», 860 (1910).
C. Noyes and Eastman, ‹Carnegie Institution Publications›,
«63», 274 (1907).
D. Luther, ‹Z. Elektroch›, «13», 296 (1907).
E. Chandler (McCoy), ‹J. Am. Chem. Soc.›, «30», 713 (1908).
F. Abbot and Bray, ‹ibid.›, «31», 760 (1909).
G. See above, p. 99.
H. Walker, ‹J. Chem. Soc.›, (London), «77», 5 (1900).
I. McCoy, ‹Am. Chem. J.›, «29», 455 (1903); Stieglitz,
‹Carnegie Institution Publications›, «107», 243 (1909).
J. Auerbach, ‹Z. phys. Chem.›, «49», 220 (1904).
K. Knox, in Abegg's laboratory, ‹Trans. Faraday Soc.›, «4», 43
(1908).
L. ‹Vide› p. 66.
[p105]
The difference in the tendencies of acids to ionize, as expressed in
the table, may be recognized in equivalent solutions by any of the
properties dependent on the ionization, such as the conductivity, the
chemical activity, the osmotic pressure and allied effects, and so
forth. If the conductivities of equal volumes of equivalent (‹e.g.›
normal) solutions of hydrochloric, phosphoric and acetic acids
are compared (‹exp.›)[190], it is readily seen that hydrochloric
acid is the best conductor, phosphoric acid a much poorer one, and
acetic acid an exceedingly poor one (the conductivity of normal
acetic acid is about 1 / 200 that of normal hydrochloric acid, and
the conductivity of normal phosphoric acid is about 1 / 14 that of
normal hydrochloric acid). Since the conductivity is approximately
proportional to the concentration of the hydrogen-ion[191] in each of
the solutions, it is evident that the hydrochloric acid is ionized
to a considerably greater extent than either of the other acids—than
acetic acid, in particular. Similarly, if a drop (0.05 c.c.) of
molar hydrochloric acid and a drop of molar acetic acid are added to
equal volumes (50 c.c.) of a very dilute solution of methyl orange
(‹exp.›), the color will be changed decidedly by the hydrochloric
acid to a bright pink, but by the acetic acid only to an orange hue.
Again, if a precipitate of barium chromate or calcium oxalate is
treated with some strong acid, hydrochloric or nitric, for instance,
it dissolves readily, while a considerable excess of acetic acid
(‹exp.›) only dissolves traces of either precipitate.[192] In this
way, the chemical behavior of these acids differs in degree, as a
result of the different tendencies to ionize, which are expressed in
the constants of the table. Advantage is taken, in analysis, of such
differences. Acetic acid, for instance, is used when only a slight
degree of acidity is desired—as in recognizing barium-ion by its
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