The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
While the constants of a large number of organic bases[194] have
been determined few constants of inorganic bases are as yet known.
The fact that the majority of ‹inorganic bases› are polyvalent and
difficultly soluble has made their examination in this respect more
difficult. From the study of the decomposition of salts by water (see
Chapter X), the trivalent bases, such as [p107] ferric hydroxide
and aluminium hydroxide, are found to be much weaker than bivalent
bases like cadmium, zinc and lead hydroxides,[195] but the data
are not sufficient for the calculation of any constants, or for
distinguishing between the ionization of the first, second and third
hydroxide groups.
The difference in ionization and in chemical activity between a
strong base, like sodium or potassium hydroxide, and a weak base,
like ammonium hydroxide, has already been discussed and illustrated
(see p. 77). In analysis, advantage is frequently taken of these
relations.[196]
«The Ionization of Salts.»—While we read and hear a good deal about
strong and weak acids, and strong and weak bases, the expression
"strong" or "weak" salt is never heard; as a matter of fact, all
salts, with very few exceptions, ionize exceedingly readily—about
as readily as the strongest acids and bases. There are minor
differences, but none of great moment—none of the kind indicated
by the wide range of constants for the acids and bases. There are
only a few important exceptions to this general rule—the most
important ones, among the common salts, being mercuric chloride
and mercuric cyanide: their exceptional behavior in regard to
ionization, as indicated by their conductivities (see below), is
found side by side with an exceptional chemical behavior, exactly
as the theory of ionization would lead us to anticipate, and it
renders necessary certain precautions, particularly in analytical
work, which will be discussed later (Chap. VI). Ordinary salts are
all ionized readily: for instance, whereas acetic acid in molar
solution is ionized only to the extent of 0.37 per cent, its salts
are highly ionized, the degree of ionization of sodium acetate, for
example, being 52.8% in molar solution. As in the case of the strong
acids and bases, salts of the type MeX, which ionize according to
the equation MeX ⇄ Me^{+} + X^{−} and which, according to the law
of chemical equilibrium, might be ‹expected› to give a constant
ratio [Me^{+}][X^{−}] / [MeX], do ‹not› give a ‹constant ratio›.
That is, when the values obtained for the concentrations of the
ions and of the nondissociated molecules, in solutions of various
[p108] strengths, are substituted in this formula, different values
are obtained.[197] For potassium chloride, we have the following
relations:
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