The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
Under certain conditions, however, a difficultly soluble substance
may be produced in a solution, in a concentration far beyond its
solubility, ‹without the separation of a precipitate› (evolution
of a gas or formation of a separate liquid) ‹and also without the
formation of a supersaturated solution›. Thus, when hydrogen sulphide
is passed into an aqueous solution of arsenious oxide, the liquid
acquires the yellow to orange color of ‹arsenious sulphide› and
becomes opalescent. But no ‹precipitate› is seen (‹exp.›), in spite
of the fact that the sulphide is extremely insoluble and is formed
practically quantitatively according to the equation As_{2}O_{3} +
3 H_{2}S ⇄ As_{2}S_{3} + 3 H_{2}O. The orange liquid passes through
a [p126] filter unchanged (‹exp.›). But if some hydrochloric acid
or a salt (‹e.g.› sodium chloride) solution is added to a portion of
it, a heavy precipitate of arsenious sulphide is immediately produced
(‹exp.›); its quantity is a good indication of the great amount of
sulphide that is ‹not› precipitated before the addition of the acid
or salt. If some pure arsenic sulphide (solid) is added to another
portion of the orange liquid, in order to overcome any possible
condition of supersaturation, the liquid is found to remain clear
(but opalescent), excepting for the few particles of added sulphide
(‹exp.›); even when it is vigorously shaken (‹exp.›), or allowed
to stand for days, no precipitate is formed. We are therefore not
dealing with a case of supersaturation.
A liquid, in which a very insoluble substance appears thus to be in
solution far beyond its usual degree of solubility, and yet does
not show at all the behavior of a supersaturated solution, is said
to contain the substance in the «colloidal condition». After a few
more instances of the colloidal condition have been presented, the
significance of the condition and the meaning of the term used to
designate it will be explained.
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