The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
EXP. A pinch of sodium chloride is brought into a platinum crucible,
which is previously heated in a blast lamp to a bright yellow heat
(1100°); then 1 c.c. of water is introduced, drop by drop. A steam
cushion is formed at once (Leidenfrost's phenomenon). After about
half of the water has been evaporated (half a minute), the water is
poured into a solution colored with blue litmus; it is changed to
red by an excess of hydrochloric acid in the water. The crucible is
cooled, and the salt remaining in it is dissolved in a little water
and the solution poured into a red litmus solution; the latter turns
blue.
The sodium chloride has obviously been partially decomposed, by the
water, into its base and its acid; the decomposition is favored by
the high temperature and by the fact that the hydrogen chloride
[p180] formed can pass through the steam cushion into the water,
while the sodium hydroxide is left behind. The removal of a product
of the decomposition would favor its progress (see. p. 114).
The conclusions concerning salts of the type of sodium chloride
may then be summarized in the statement, that ‹salts formed by the
union of a very strong base with an equally strong acid are only
very slightly decomposed by water and their solutions show a neutral
reaction›.
The decomposition of a salt by water into its component base and acid
is called ‹hydrolysis› and the salt is said to be ‹hydrolyzed› in the
action.
«Action of Water on the Salt of a Strong Base with a Weak Acid.»—The
relations are similar in principle, but quite different in degree and
in net result, when the salt of a very strong base, combined with a
weak acid, is dissolved in water. Potassium cyanide is a typical salt
of this kind, and the study of its hydrolysis will illustrate the
behavior of this class of salts. The hydrolysis takes place according
to the equations
«KCN» ⇄ «K»^{+} + «CN»^{−}
«HOH» ⇄ «HO»^{−} + H^{+}
K^{+} + HO^{−} ⇄ KOH
CN^{−} + H^{+} ⇄ «HCN».
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