The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
[389] The comparative stability of this basic salt represents
an instance of the different ionizing power, or basic
strength, of the three hydroxide groups of a trivalent base
(see p. 106). The hydrolysis of ferric chloride seems to
involve, primarily, only the third or least ionizable of the
hydroxide groups of ferric hydroxide, and the hydrolysis,
except in extreme dilution, proceeds chiefly according to
Fe^{3+} + 3 Cl^{−} + HOH ⇄ Fe(OH)^{2+} + 3 Cl^{−} + H^{+}. ‹Vide›
Goodwin, ‹Z. phys. Chem.›, «21», 1 (1896). In the case of the
salt of the much weaker acid, carbonic acid, the hydrolysis goes
further, involving two hydroxide groups of ferric hydroxide and, to
some extent, all three.
[390] The extreme insolubility of Al(OH)_{3}, Fe(OH)_{3} and
Cr(OH)_{3}, together with their weakness as bases, facilitates
their precipitation (see pp. 185–6).
[391] There is a ‹small degree of hydrolysis› (see footnote, p.
189), but the hydroxides of the zinc group are not sufficiently
insoluble to be precipitated under these conditions.
[392] ‹Cf.› A. A. Noyes, Bray and Spear, ‹J. Am. Chem. Soc.›, «30»,
496 (1908).
[393] ‹Cf. The Elements of the Differential and Integral Calculus›,
based on Nernst and Schönflies's ‹Lehrbuch, etc.›, by Young and
Linebarger, pp. 363 and 364 (1900).
[394] Losses due to the tendency of aluminium hydroxide to assume
the colloidal condition (p. 136) must be guarded against by other
precautions (‹loc. cit.›).
[p199]
CHAPTER XI
«THE COPPER AND SILVER GROUPS. PRECIPITATION WITH HYDROGEN SULPHIDE»
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