The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
It is a significant fact that the equivalent conductivity of
hydrochloric acid is ‹close to its limit even at finite dilutions›,
and that the same relation holds for the strong acids and the
strong bases, in general, and for most salts. But the equivalent
conductivity of weak acids, like acetic acid, and of weak bases, like
ammonium hydroxide, in finite dilutions is still far removed from
the limits which may be calculated for infinite dilutions. Arrhenius
was led then to the further important conclusion that, in the case
of the first electrolytes mentioned, a ‹very large proportion of the
electrolyte must exist in the ionized form at finite concentrations›,
their equivalent conductivities having almost reached the limit
characteristic of infinite dilution.
«Clausius's Theory of Ionization and the Modern Theory.»—It
is in these conclusions—in particular that the proportion of
ionized electrolyte ‹may be determined experimentally›, and that
frequently a ‹large proportion is found to be ionized at finite
concentrations›,—that the ‹modern theory of ionization differs from
the older theory of Clausius›. The former is an elaboration of the
latter, and some opponents[83] of the modern theory still uphold
the latter as offering an adequate explanation of the phenomena
of conductivity. All facts, then, in particular, which confirm
the validity of the ‹conception of the degree of ionization›, as
introduced by Arrhenius, [p052] must be considered as criteria
favoring his theory, specifically. The development of chemistry in
the last twenty years is replete with such evidence and we shall meet
it in many connections throughout our work.
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