The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
Clausius[84] also assumed dissociated molecules or ions to be the
real carriers of electricity in the passage of a current through the
solution of an electrolyte, but he assumed only a ‹minute quantity
of these molecular fragments or ions to be free at any moment›,
their existence being supposed to be transitory and dependent in
particular on exchanges of atoms between molecules. As a result of
the oscillations of the atoms composing a molecule, oscillations
comparable with the motions of molecules assumed in the kinetic
theory of gases, molecules were considered by Clausius occasionally
to reach such a condition of instability, that they dissociated
into smaller particles; since the atoms were supposed to be held
in a molecule by attractions of electrical charges on the atoms
(theory of Berzelius), the fragments of the molecule would carry the
charges, positive and negative respectively, which they possessed
in the molecule. Such a breaking up or dissociation of molecules
was, further, supposed to occur with particular ease during the
collisions of molecules, the electrical attractions and repulsions
of the charged atoms favoring, at such moments, an ‹exchange of
atoms›. During the exchange, the atoms were considered to be free
molecules, charged with electricity—essentially ions,—capable
of moving under the influence of electrical forces and of thus
carrying a current. Finally, such ions were supposed, in part, to
escape recombination, and to remain free, until each ion either
collided and combined with an ion of opposite charge, or collided
with a molecule and displaced an atom of the same charge from that
molecule, a new ion being thus liberated. The theory, as usually
interpreted, assumed the existence of only a very small quantity of
such free ions, that being all that was supposed to be required to
explain the facts known at the time it was advanced.
In what follows, we shall confine the discussion strictly to such
contrasts between the two theories as grow out of a consideration
of the phenomena of conductivity, and particularly consider some
evidence which is directly concerned with the conductivity of
solutions.
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