The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
The conductivity of a solution must be made up, therefore, of the
sum of the shares which the positive ions and the negative ions,
respectively, take in carrying the current. This principle was first
advanced by Kohlrausch. The share of each kind of ion in conducting
a current may be determined, for hydrochloric acid for instance,
in the following way: A porous diaphragm may be used to divide the
solution in an electrolytic cell into two halves, the concentration
of the acid being the same in both halves (represented, as indicated
in Fig. 11, by 15 molecules[89] of ionized acid in each half). A
measured current is passed through the solution, say, sufficient to
liberate 3 molecules of hydrogen H_{2}, and 3 of chlorine Cl_{2},
corresponding to 6 ‹ions› of each, and the concentration of the acid
in each half is then again determined by analysis. Say it is found
to correspond to 14 molecules of hydrochloric acid in the half of
the solution on the side of the cathode and 10 molecules in the half
on the side of the anode (see Fig. 12). Then the anode half has lost
5 ions of hydrogen, which must have passed through the diaphragm
toward the cathode and taken the place of five of the six hydrogen
ions discharged at the cathode. Similarly, the solution around the
cathode has lost one chloride ion, which must have passed through
the diaphragm toward the anode, and the hydrogen-ion corresponding
to it, remaining on the right side without a compensating negative
ion, must be the sixth hydrogen-ion discharged at the cathode. In
other words, five hydrogen ions passed to the right, while one
chloride ion passed to the left. The hydrogen ions then carried
five-sixths of the current through the diaphragm, and consequently
through the solution, and the chloride ions only one-sixth of the
current. Since the solutions were of equal concentration to start
with, the hydrogen ions have moved ‹five times as fast› toward the
cathode as the chloride ions have moved toward the anode.
[Illustration: FIG. 11.]
[Illustration: FIG. 12.]
The equivalent conductivity of 0.1-molar hydrochloric acid is 351
at 18°, and experiment shows that the hydrogen-ion carries 84% of
the current, the chloride-ion only 16%. The conductivity may then be
considered to be the [p056] sum of the share the hydrogen-ion has
in carrying the current, ‹i.e.› 0.84 × 351, or 295, and of the share
of the chloride-ion, 0.16 × 352.5, or 56. These values may be called
the ‹equivalent partial conductivities› or ‹mobilities› of the ions
in this solution.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account