The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
from the concentrated to the dilute acid, would therefore be held
back by the powerful attraction between their positive charges and
the negative charges left in the concentrated acid (on the Cl^{−}
ions). The separation of the electrical charges, incidental to a
faster diffusion of hydrogen ions, if it occurred, would result,
therefore, in the development of electrical forces of attraction,
which would prevent a separation of the oppositely charged particles
beyond any but distances too small to be measured. It would follow,
however, that no difficulty whatever should be experienced in
‹observing such a separation›, as a result of unequal rates of
migration of the ions in question, ‹if provision were made to
preserve electrical neutrality in all zones› of the two solutions,
‹i.e.› if provision is made for the immediate discharge of the ions,
as they separate by the unequal rates of diffusion. For instance, the
part of the liquid into which the positive hydrogen ions move more
rapidly, charging it with positive electricity, may be connected, by
means of a wire, with the part of the liquid to which the chloride
ions, left behind by their slower movements, are imparting a negative
charge. In such a circuit, a current of electricity should be
produced, the positive current flowing through the wire from the
dilute to the concentrated acid. As a matter of fact, we find that a
current is produced, when these conditions are observed.
EXP. The lower plate in an Arrhenius cell is covered with
concentrated hydrochloric acid. Very dilute acid is allowed to flow
slowly on to the surface of the concentrated acid, from a pipette
with a curved, narrow point, until the upper plate is submerged. The
two plates are connected with a sensitive galvanometer. The current
flows in the direction demanded by the observed mobilities of the
ions, the positive current entering the galvanometer from the plate
covered by the dilute solution, which is charged positively by the
faster moving hydrogen ions coming from the concentrated solution.
If the cell is [p061] connected with the electrodes of a very
small cell containing copper sulphate, in the course of twenty-four
hours quite a deposit of metallic copper is formed on the electrode
connected with the concentrated solution of hydrochloric acid.
The existence of the products of the electrolytic dissociation, of
hydrochloric acid may therefore be demonstrated,[96] by the aid
of the individual diffusion of the products of the dissociation,
in the same way as was the coëxistence of the products of the
gaseous dissociation of ammonium chloride, when the conditions
for the experiment are adapted to the nature of the dissociation
products. Cells of this type, depending for their current on unequal
concentrations of given ions, are called "concentration cells."
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