The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
The question may be raised, why the first solvents mentioned
should have the power to cause ionization, while the second series
of solvents named do not have this power, or have it only to a
very slight extent. Without attempting to enter into an elaborate
discussion of this important question, it may be said that J. J.
Thomson[101] and Nernst[102] suggested that the ionizing powers
of solvents must be intimately connected with their ‹dielectric
behavior›, and this view has now been well established. It may be
said, in simple terms, that the so-called dielectric constant of
a solvent determines the force with which electrical charges will
attract and repel each other; the higher the dielectric coefficient
of a medium, the ‹smaller will be the attraction between opposite
electrical charges›, other conditions being the same. In solvents,
then, of high dielectric powers, the coëxistence of oppositely
charged particles must be more favored than in solvents of low
dielectric powers. The dielectric constants of a number of solvents
are given in the following table: [p063]
Hydrogen cyanide, HNC 95
Hydrogen peroxide, H_{2}O_{2} 93
Water, H_{2}O 81
Methyl (wood) alcohol, CH_{4}O 32
Ethyl (ordinary) alcohol, C_{2}H_{6}O 22
Ammonia, H_{3}N 22
Chloroform, CHCl_{3} 5
Ether, (C_{2}H_{5})_{2}O 4
Benzene, C_{6}H_{6} 2
It is quite apparent that the good ionizing media have, as a matter
of fact, the highest constants; those which cause ionization, at most
minimally (‹e.g.› benzene), the lowest.
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