The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
action, the same as the similar [p086] action in aqueous solution
has been proved to be by quantitative measurements.[156] Only exact
measurements, comparable with those made in aqueous solutions, can
settle the question at issue, and until such quantitative evidence
is forthcoming, a definite conclusion that the action of hydrogen
chloride in benzene solution is or is not an ionic action is not
warranted by the facts.
Equally interesting are Kahlenberg's observations of interaction
between hydrogen chloride in benzene solution and a similar solution
of copper oleate. Each solution shows absence of appreciable
conductivity, yet, when the solutions are mixed, precipitation
of copper chloride occurs instantly. Whether we have here an
instantaneous action between non-ionized molecules, as claimed by
the observer, or whether the minimal ionization[157] of the hydrogen
chloride and copper oleate, the existence of which we have a right
to assume, is sufficient to account for this rapid action, both
components being in solution and intimately mixed, is a question
of the greatest interest. But until quantitative measurements of
all the factors involved in chemical actions in benzene solution
are obtained, a very difficult, but necessary task, which the
discoverer of the action omitted to perform, no definite conclusion
whatever can be based on such results, interesting as they are.
Water, although it is only minimally ionized (tables, Chapter VI),
hydrolyzes salts like potassium cyanide and aluminium chloride
almost instantly, and it has been rigorously proved that the
resulting condition of equilibrium involves the ‹ions of water›[158]
(Chapter X). With the possibility that the well-known enormous
speeds of action of ions may completely offset the tremendous
reduction in concentration of the hydrogen-ion, in a benzene
solution of hydrogen chloride as compared with an aqueous solution,
further analysis of the relations is imperative.[159] Until such
investigations have been carried out, we must consider [p087] it
possible that the reactions of hydrogen chloride in benzene solution
may be reactions of its non-ionized molecules or reactions of its
ions. In view of the undoubted minute concentrations of the latter,
as compared with aqueous solutions, and in view of the inertness of
non-ionized hydrogen chloride in aqueous solutions as compared with
the activity of its ions, a benzene solution of hydrogen chloride
should show far less ionic activity than an aqueous solution,
and that such is the case is brought out clearly by Kahlenberg's
interesting experiments.
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