The Energy System of Matter: A Deduction from Terrestrial Energy PhenomenaWeir, James, active 1883-1912
Science
The Energy System of Matter: A Deduction from Terrestrial Energy Phenomena
Weir, James, active 1883-1912
Force and energy
Keeping in view these general considerations, it is now proposed to
estimate, under ordinary terrestrial atmospheric conditions, the total
energy properties of the three gaseous substances, oxygen, nitrogen, and
aqueous vapour. The information relative to the energy calculation which
is in the meantime available is shown below in tabular form. As far as
possible all the heat and other energy properties of each substance as
it cools to absolute zero have been taken into account.
_Table of Properties_
+--------+---------+----------+----------+-------------+-------+---------+
| I | II | III | IV | V | VI | VII |
+--------+---------+----------+----------+-------------+-------+---------+
| |Specific | Evaporation | | | |
| | Heat at |Temperature of Liquid| Approximate | Latent| Vapour |
| Gas | Constant| at Atmospheric | Latent Heat |Heat of|Pressure.|
| |Pressure.| Pressure. |of Gas 50° F.|Liquid.| 50° F. |
| | | °F. °F. (Abs.)| | | |
+--------+---------+----------+----------+-------------+-------+---------+
|Oxygen | 0·2175 | -296 | 164 | 100 | ... | ... |
+--------+---------+----------+----------+-------------+-------+---------+
|Nitrogen| 0·2438 | -320 | 141 | 100 | ... | ... |
+--------+---------+----------+----------+-------------+-------+---------+
|Aqueous | | | | | | |
|Vapour | 0·4 | 212 | 673 | 1080 | 144 | 0·176 |
+--------+---------+----------+----------+-------------+-------+---------+
Since no reliable data can be obtained with regard to the values and
variations of specific heats at extremely low temperatures, they are
assumed for the purpose of our calculation to be in each case that of
the gas, and to be constant under all conditions. Latent heats are
utilised in every case when available.
With these reservations, the total energy, referred to absolute zero, of
one pound of oxygen gas at normal temperature of 50° F. or 511° F.
(Abs.) will be approximately
(511 × 0·2175) + 100 = 211 Thermal Units Fahrenheit.
This in work units is roughly equivalent to
211 × 778 = 164,000 ft. lbs.
Adopting the same method with nitrogen gas, its energy at the same
initial temperature will be, per unit mass,
174,600 ft. lbs.
There is thus a somewhat close resemblance, not only in the general
temperature conditions but also in the energy conditions, of the two
gases oxygen and nitrogen.
It will be readily seen, however, that under the same conditions the
energy state of aqueous vapour differs very considerably from either,
for by the same method as before the energy per pound of aqueous vapour
is equal to
{(511 × 0·4) + 1080 + 144} × 778 = 1,111,000 ft. lbs.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account