The kinetic theory of gases supposes them to be made up of minute
particles all alike, which are perfectly elastic and are travelling
hither and thither at great speeds in practically straight lines. In
consequence, these are forever colliding among themselves, giving and
taking velocities with bewildering rapidity, resulting in a state of
confusion calculated to drive a computer mad. Somebody has likened a
quiet bit of air to a boiler full of furious bees madly bent on getting
out. The simile flatters the bees. To follow the vicissitudes of any
one molecule in this hurly-burly would be out of the question; still
more, it would seem, that of all of them at once. Yet no less Herculean
a task confronts us. To find out about their motions, we are therefore
driven to what is called the statistical method of inquiry,—which is
simply a branch of the doctrine of probabilities. It is the method
by which we learn how many people are going to catch cold in Boston
next week when we know nothing about the people, or about colds, or
about catching them. At first sight it might seem as if we could never
discover anything in this hopelessly ignorant way, and as if we had
almost better call in a doctor. But in the multitude of colds—not of
counsellors—lies wisdom. So in other things not hygienic. As you cannot
possibly divine, for instance, what each boy in town is going to do
during the year, nor what is his make of mind, how can you say whether
he will accidentally discharge a firearm and shoot his playmate or not!
And yet if you take all the boys of Boston, you can predict to a nicety
how many will thus let off a gun and “not know that it was loaded.”
In this only genuine method of prophecy, complete ignorance of all the
actual facts, we are able without knowing anything whatever about each
of the molecules to predicate a good deal about them all. To begin
with, the pressure a gas exerts upon the sides of a vessel containing
it must be the bombardment the sides receive from the little molecules;
and the heating due this rain of blows, or the temperature to which the
vessel is raised, must measure their energy of translation. On this
supposition it is found that the laws of Avogadro and of Boyle are
perfectly accounted for, besides many more properties of gases which
the theory explains, and as nothing yet has been encountered seriously
contradicting it, we may consider it as almost as surely correct as the
theory of gravitation. To three great geniuses of the last century we
owe this remarkable discovery—Clausius, Clerk Maxwell, and Boltzmann.
Public-domain text, read in full here on John Shaqi.
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