The filtration of public water-supplies: Third edition, revised and enlarged.Hazen, Allen
Science
The filtration of public water-supplies: Third edition, revised and enlarged.
Hazen, Allen
Filters and filtration; Water-supply
_Compounds of Manganese._—Manganese forms compounds similar to those
of iron, that is to say manganous and manganic salts, but their use
in connection with water filtration has not been found possible. In
addition, manganese forms a series of compounds, known as manganates
and permanganates, quite different in their structure and action from
the others. These compounds contain an excess of oxygen which they
give up very readily to organic matters capable of absorbing oxygen,
and because of this power, they have been extensively used in the
treatment of sewage. Applied to the treatment of waters their action is
very slight, and the compounds are so expensive that they have not been
employed for this purpose. Theoretically the action is very attractive,
as the oxygen liberated by their decomposition oxidizes some of the
organic matter of the water, thereby purifying it in part, while the
manganese is precipitated as a flocculent precipitate having all of
the advantages pertaining to a precipitate of hydrate of alumina, and
without the disadvantage of adding acid to the water, as is the case
with the compounds of alumina and iron. These chemicals, when used in
comparatively concentrated condition, have powerful germicidal actions,
but in water purification the amounts which can be used are so small
that no action of this kind results. The amount which can be applied to
a water is limited to the amount which can be decomposed by the organic
matters present in the water, and is not large.
_The Use of Metallic Iron and Aluminum, with the Aid of
Electricity._—Elaborate experiments were made at Louisville with
metallic iron and aluminum oxidized and made available by the aid of
electric currents. The use of iron with electric currents was tried
in sewage purification some years ago, under the name of the Webster
process, but was never put to practical use. The theory is to oxidize
the iron or aluminum in contact with the water, with the formation
of flocculent hydrates, by the aid of an electric current, thereby
securing the advantages of the application of salts of these metals to
the water without the disadvantage of the addition of acid.
_Other Chemicals Employed._—A solution containing chlorine produced
by electrical action has been suggested. Chlorine is a powerful
disinfectant, and when used in large quantities kills bacteria. It is
not possible to use enough chlorine to kill the bacteria in the water
without rendering it unfit for human use. The nature of this treatment
has been concisely described by Dr. Drown,[36] who shows that the
electrically prepared fluids do not differ in their action in any way
from well-known chemicals, the use of which would be hardly considered.
The use of ozone and peroxide of hydrogen have also been suggested, but
I do not know that they have been successfully used on a large scale.
The same is true of many other chemicals, the consideration of which is
hardly necessary in this connection.
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