The filtration of public water-supplies: Third edition, revised and enlarged.Hazen, Allen
Science
The filtration of public water-supplies: Third edition, revised and enlarged.
Hazen, Allen
Filters and filtration; Water-supply
AMOUNT OF IRON REQUIRED TO RENDER WATER OBJECTIONABLE.
Three hundredths of a part in 100,000 of metallic iron very rarely
precipitate or cause any trouble. Five hundredths occasionally
precipitate, and this amount may be taken as about the allowable
limit of iron in a satisfactory water. One tenth of a part is quite
sure to precipitate and give rise to serious complaint. Two or three
tenths make the water entirely unsuitable for laundry purposes, and
are otherwise seriously objectionable, and will hardly be tolerated
by a community. Under some conditions ground-waters carry as much
as 1 part in 100,000 of iron, and such waters are hardly usable. In
iron-removal plants an effluent containing less than 0.05 is regarded
as satisfactory. One containing less than 0.02, as is the case with
many plants, is all that can be desired. The percentage of removal is
of no significance, but only the amount left in the effluent.
CAUSE OF IRON IN GROUND-WATERS.
Natural sands, gravels, and rocks almost always contain iron, often in
considerable amount. The iron is usually combined with oxygen as ferric
oxide, and in this condition it is insoluble in water. Water passing
through iron containing materials will not ordinarily take up iron.
When, however, the water contains a large amount of organic matter in
solution, this organic matter takes part of the oxygen away from the
iron, and reduces the ferric oxide to ferrous oxide. The ferrous oxide
combines with carbonic acid, always present under these conditions,
forming ferrous carbonate, which is soluble and which goes into
solution.
Surface-waters nearly always carry free oxygen, and when such waters
enter the ground they carry oxygen with them, and the organic matters
in the water use up the free oxygen before they commence to take oxygen
away from the iron of the ground. It is thus only in the presence of
organic matters, and in the absence of free oxygen, that the solution
of iron is possible. It sometimes happens that the organic matters
which reduce the iron are contained in the soil itself, in which
case iron may be taken up even by water originally very pure, as for
instance, by rain-water.
Generally speaking, iron is everywhere present in sufficient quantity
in the strata from which ground-waters are obtained, and wherever the
conditions of the organic matters and oxygen necessary for solution
occur, iron-containing waters are secured, and the iron is usually
present in the earth in such quantity that the water can dissolve as
much as it will take up for a long series of years, or for centuries,
without exhausting the supply. There is thus little prospect of
improvement of such waters from exhaustion of the supply of iron.
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