The filtration of public water-supplies: Third edition, revised and enlarged.Hazen, Allen
Science
The filtration of public water-supplies: Third edition, revised and enlarged.
Hazen, Allen
Filters and filtration; Water-supply
The method was open to the serious objections that the hues of the
standards did not match closely the hues of the waters; that the colors
produced with different lots of Nessler reagent differed considerably,
and therefore the exact values of results were more or less uncertain;
and further, that the numbers obtained for color were not even
approximately proportional to the amounts of coloring matter present.
Because of this peculiarity, in filtration the percentage of color
removal, as determined by the use of these standards, is not even
approximately correct, but is much above the truth.
In the Lovibond tintometer, which has been extensively used in England,
the standards of color are based upon the colors of certain glass
slips, which are in turn compared with standard originals kept for
that purpose. This process answers quite well, but is open to some
objections because of possible uncertainties in the standardization of
the units.
Another method of measuring colors is to compare them with dilute
solutions of platinum and cobalt. The ratio of cobalt to platinum can
be varied to make the hue correspond very closely with the hues of
natural waters, and the amount of platinum required to match a water
affords a measure of its color, one part of metallic platinum in 10,000
parts of water forming the unit of color.
This standard has the advantages that it can be readily prepared with
absolute accuracy in any laboratory, and that by varying the ratio of
platinum to cobalt the hues of various waters can be most perfectly
matched. It is important that the observations should not be made in
too great a depth, as the discrepancy in hues increases much more
rapidly than the depth of color.
For further information regarding colors the reader is referred to
articles in the American Chemical Journal, 1892, vol. xiv, page 300;
Journal of the American Chemical Society, vol. ii, page 8; vol. xviii,
1896, pp. 68, 264, and 484; Journal of the Franklin Institute, Dec.
1894, p. 402; Journal of the New England Water Works Association, vol.
xiii, 1898, p. 94.
AMOUNT OF COLOR IN AMERICAN WATERS.
New England surface-waters have colors ranging from almost nothing
up to 2.00. The colors of the public water-supplies of Massachusetts
cities have been recorded in the reports of the State Board of Health
for some ten years. The figures given were recorded first upon the
Nessler standard, and afterwards upon a modification of the same, known
as the natural water standard. The figures given are approximately
equal to those for the platinum color standard, the relations between
the two having been frequently determined by various observers and
published in the above-mentioned papers. The accompanying diagram shows
the colors in several Massachusetts supplies, as plotted from the
figures given in the published reports.
[Illustration: FIG. 18.—COLORS OF WATERS.
(Analyses of the Mass. State Board of Health.)]
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