The Forms of Water in Clouds and Rivers, Ice and GlaciersTyndall, John
Science
The Forms of Water in Clouds and Rivers, Ice and Glaciers
Tyndall, John
Clouds; Glaciers; Ice; Rivers; Water
433. It is only substances which _expand_ on solidifying that behave
in this manner. The metal bismuth, as we know, is an example similar
to water; while lead, wax, or sulphur, all of which contract on
solidifying, have their point of fusion _heightened_ by pressure.
434. And now you are prepared to understand Professor James Thomson's
theory of regelation. When two pieces of ice are pressed together
liquefaction, he contends, results. The water spreads out around the
points of pressure, and when released re-freezes, thus forming a kind
of cement between the pieces of ice.
§ 63. _Faraday's View of Regelation._
435. Faraday's view of regelation is not so easily expressed, still
I will try to give you some notion of it, dealing in the first place
with admitted facts. Water, even in open vessels, may be lowered many
degrees below its freezing temperature, and still remain liquid;
it may also be raised to a temperature far higher than its boiling
point, and still resist boiling. This is due to the mutual cohesion
of the water particles, which resists the change of the liquid
either into the solid or the vaporous condition.
436. But if into the over-chilled water you throw a particle of ice,
the cohesion is ruptured, and congelation immediately sets in. And if
into the superheated water you introduce a bubble of air or of steam,
cohesion is likewise ruptured, and ebullition immediately commences.
437. Faraday concluded that _in the interior_ of any body, whether
solid or liquid, where every particle is grasped so to speak by the
surrounding particles, and grasps them in turn, the bond of cohesion
is so strong as to require a higher temperature to change the state
of aggregation than is necessary _at the surface_. At the surface
of a piece of ice, for example, the molecules are free on one side
from the control of other molecules; and they therefore yield to
heat more readily than in the interior. The bubble of air or steam
in overheated water also frees the molecules on one side; hence the
ebullition consequent upon its introduction. Practically speaking,
then, the point of liquefaction of the interior ice is higher than
that of the superficial ice. Faraday also refers to the special
solidifying power which bodies exert upon their own molecules.
Camphor in a glass bottle fills the bottle with an atmosphere of
camphor. In such an atmosphere large crystals of the substance may
grow by the incessant deposition of camphor molecules upon camphor,
at a temperature too high to permit of the slightest deposit _upon
the adjacent glass_. A similar remark applies to sulphur, phosphorus,
and the metals in a state of fusion. They are deposited upon solid
portions of their own substance at temperatures not low enough to
cause them to solidify against other substances.
Public-domain text, read in full here on John Shaqi.
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