You know that in this theory all the properties of gases are explained
by a simple hypothesis; it is supposed that all the gaseous molecules
move in every direction with great velocities and that they follow
rectilineal paths which are disturbed only when one molecule passes very
near the sides of the vessel or another molecule. The effects our crude
senses enable us to observe are the mean effects, and in these means,
the great deviations compensate, or at least it is very improbable that
they do not compensate; so that the observable phenomena follow simple
laws such as that of Mariotte or of Gay-Lussac. But this compensation of
deviations is only probable. The molecules incessantly change place and
in these continual displacements the figures they form pass successively
through all possible combinations. Singly these combinations are very
numerous; almost all are in conformity with Mariotte's law, only a few
deviate from it. These also will happen, only it would be necessary to
wait a long time for them. If a gas were observed during a sufficiently
long time it would certainly be finally seen to deviate, for a very
short time, from Mariotte's law. How long would it be necessary to wait?
If it were desired to calculate the probable number of years, it would
be found that this number is so great that to write only the number of
places of figures employed would still require half a score places of
figures. No matter; enough that it may be done.
I do not care to discuss here the value of this theory. It is evident
that if it be adopted, Mariotte's law will thereafter appear only as
contingent, since a day will come when it will not be true. And yet,
think you the partisans of the kinetic theory are adversaries of
determinism? Far from it; they are the most ultra of mechanists. Their
molecules follow rigid paths, from which they depart only under the
influence of forces which vary with the distance, following a perfectly
determinate law. There remains in their system not the smallest place
either for freedom, or for an evolutionary factor, properly so-called,
or for anything whatever that could be called contingence. I add, to
avoid mistake, that neither is there any evolution of Mariotte's law
itself; it ceases to be true after I know not how many centuries; but at
the end of a fraction of a second it again becomes true and that for an
incalculable number of centuries.
Public-domain text, read in full here on John Shaqi.
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