The imposing simplicity of Mayer's principle likewise contributes to
strengthen our faith. In a law deduced immediately from experiment, like
Mariotte's, this simplicity would rather seem to us a reason for
distrust; but here this is no longer the case; we see elements, at first
sight disparate, arrange themselves in an unexpected order and form a
harmonious whole; and we refuse to believe that an unforeseen harmony
may be a simple effect of chance. It seems that our conquest is the
dearer to us the more effort it has cost us, or that we are the surer of
having wrested her true secret from nature the more jealously she has
hidden it from us.
But those are only little reasons; to establish Mayer's law as an
absolute principle, a more profound discussion is necessary. But if this
be attempted, it is seen that this absolute principle is not even easy
to state.
In each particular case it is clearly seen what energy is and at least a
provisional definition of it can be given; but it is impossible to find
a general definition for it.
If we try to enunciate the principle in all its generality and apply it
to the universe, we see it vanish, so to speak, and nothing is left but
this: _There is something which remains constant_.
But has even this any meaning? In the determinist hypothesis, the state
of the universe is determined by an extremely great number _n_ of
parameters which I shall call x_{1}, x_{2},... x_{_n_}. As soon as
the values of these _n_ parameters at any instant are known, their
derivatives with respect to the time are likewise known and consequently
the values of these same parameters at a preceding or subsequent instant
can be calculated. In other words, these _n_ parameters satisfy _n_
differential equations of the first order.
These equations admit of _n_ - 1 integrals and consequently there are
_n_ - 1 functions of x_{1}, x_{2},... x_{_n_}, which remain constant.
_If then we say there is something which remains constant_, we only
utter a tautology. We should even be puzzled to say which among all our
integrals should retain the name of energy.
Besides, Mayer's principle is not understood in this sense when it is
applied to a limited system. It is then assumed that _p_ of our
parameters vary independently, so that we only have _n_ - _p_ relations,
generally linear, between our _n_ parameters and their derivatives.
To simplify the enunciation, suppose that the sum of the work of the
external forces is null, as well as that of the quantities of heat given
off to the outside. Then the signification of our principle will be:
_There is a combination of these n - p relations whose first member is
an exact differential_; and then this differential vanishing in virtue
of our _n_ - _p_ relations, its integral is a constant and this integral
is called energy.
Public-domain text, read in full here on John Shaqi.
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