The Galaxy, April, 1877: Vol. XXIII.—April, 1877.—No. 4.Various
General
The Galaxy, April, 1877: Vol. XXIII.—April, 1877.—No. 4.
Various
American literature -- Periodicals
difficulties must prevent the utilization of these discoveries in this
direction, even if they should prove to be in themselves all that is
hoped. The retinal picture has not yet been photographed, but it seems
probable, from the above recounted experiments, that it can be.
ACTION OF ORGANIC ACIDS ON MINERALS.
DR. H. C. BOLTON of the New York School of Mines has made the
interesting discovery that minerals may be decomposed by boiling with
organic acids, just as they are by treatment with the strong mineral
acids. He has tried the action of such acids as citric, tartaric,
oxalic, acetic, malic, and other acids, on finely powdered carbonates,
silicates, sulphides, and other classes of mineral. All the carbonates
examined (fourteen in number) dissolved with effervescence, sulphides
were decomposed with evolution of sulphuretted hydrogen, and silicates
with formation of gelatinous silica. This important discovery will
greatly add to the resources of the mineralogist, who is compelled to
do much of his work in the field. Hitherto he has been debarred from
using the mineral acids (the action of which sometimes forms a decisive
test) by the impossibility of carrying them in the pocket or wallet
without danger. The organic acids are solid, and can be conveniently
stowed away. Their action, however, is not so decided as that of the
mineral acids, but this is not always a defect, but offers additional
means of determination. For example, all the specimens of bornite and
pyrrhotite examined yielded sulphuretted hydrogen with tartaric,
citric, and oxalic acids, but chalcopyrite and pyrite do not. On the
other hand, the use of the organic acids may give rise in some cases to
the formation of nitric acid, which in its nascent condition will
afford a very powerful agent of decomposition. Thus all the sulphides
examined (seventeen), with the exception of molybdenite and cinnabar,
were quickly attacked by citric or tartaric acid, to which a little
potassium nitrate had been added. Potassium chlorate produces a similar
though slower action. These examples are sufficient to show that Dr.
Bolton has found a promising field of inquiry, and, singular to say,
considering the attention which the action of organic acids has
received, it is a field believed to be entirely new. He is continuing
his researches.
SCIENTIFIC ORCHESTRATION.
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