The Gallery of Portraits: with Memoirs. Volume 4 (of 7)Malkin, Arthur Thomas
History
The Gallery of Portraits: with Memoirs. Volume 4 (of 7)
Malkin, Arthur Thomas
Biography
In the space to which we are restricted, it will be impossible to give
an adequate idea of the vast importance of Dr. Priestley’s chemical
discoveries: they are justly regarded as forming the basis of our
knowledge of pneumatic chemistry, and indeed of the science in general;
for upon one of them alone, that of oxygen gas, is founded our
acquaintance with the nature of air, earth, and water, and the same
discovery has served also to explain the action of fire.
Dr. Priestley’s residence at Leeds was near a brewery; and his first
pneumatic experiments were made on the carbonic acid gas, or _fixed
air_, largely generated during fermentation. Gradually pursuing the
subject, he examined various other aëriform bodies, and submitted to
experiment numerous substances which were convertible into, or capable
of yielding, air. These investigations led him to the discovery of new
gaseous bodies, both elementary and compound. So little cultivated had
been the field in which he commenced his researches, that he was under
the necessity of imagining and constructing new instruments, in order to
carry them on. To his inventive genius chemistry is indebted for the
pneumatic trough, the method of receiving and retaining gases over
mercury, and the process of combining and decomposing them by
electricity. “The very implements,” Dr. Henry remarks, in his Estimate
of the Philosophical Character of Dr. Priestley, “with which he was to
work were, for the most part, to be invented; and of the merits of those
which he did invent, it is a sufficient proof that they continue in use
to this day, with no very important modification. All his contrivances
for collecting, transferring, and preserving different kinds of air, and
for submitting those airs to the action of solid and liquid substances,
were exceedingly simple, beautiful, and effectual. They were chiefly,
too, the work of his own hands, or were constructed under his directions
by unskilled persons.” Dr. Priestley’s first publication on pneumatic
chemistry appeared in 1772; it was called “Directions for impregnating
Water with fixed Air,” &c. &c. In this work he proposed the use of a
condensing engine for the purpose of causing the water to dissolve a
larger quantity of the gas, and thus to prepare artificial mineral
waters: this plan, it is well known, is now practised to a great extent.
In the Philosophical Transactions for 1772, he announced the discovery
that air, which had been vitiated by respiration or the burning of
candles, was restored by the vegetation of plants; that air exposed to a
mixture of sulphur and iron filings, as had previously been done by
Hales, was diminished by about one-fourth or one-fifth in bulk, and that
the residual air was lighter than atmospheric air, and noxious to
animals. This diminished air he afterwards called phlogisticated air; it
is now named azotic, or nitrogen gas. The discovery of this fluid is
generally attributed to Dr. Rutherford, who, in his treatise “De Aëre
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