The Gallery of Portraits: with Memoirs. Volume 7 (of 7)Malkin, Arthur Thomas
History
The Gallery of Portraits: with Memoirs. Volume 7 (of 7)
Malkin, Arthur Thomas
Biography
Such were the notions which prevailed on the subject prior to the
commencement of Dr. Black’s researches. No one advanced, or seemed to
have any desire to advance, a step nearer to the truth: yet the whole
was a mere question of fact, and a fact of the most obvious nature. In
this we cannot fail to observe one of those instructive instances, which
the history of science often brings before us, of the unaccountable
blindness, even of inquiring minds, to truths constantly before their
eyes, or, if perceived, to the importance of their being thoroughly
examined. A very little consideration ought to have shown any observer,
that the gain or loss of heat in the cases in question is by no means
slight or trifling in amount: yet no one thought of this till Dr. Black
pointed it out; and no one reasoned upon it, or perceived its bearing,
till that philosopher showed the curious inference to be drawn from it.
The case was simply this:—Two equal vessels, one full of water just at
the freezing temperature, the other of actual ice, are brought into a
warm room. In a short time the water acquires the temperature of the
room. Exactly the same quantity of heat has been communicated to the
vessel of ice; yet, at the end of the same time, it is found to retain
precisely the same temperature as at first. A considerable part of it
indeed has been melted, but it may take several hours more to melt the
whole. Until that change is completed, the temperature does not vary a
single degree. As soon as all the ice is liquefied, and not before, the
temperature of the mass begins to rise, and proceeds to increase, from
this time, as rapidly as that of the water in the other vessel did
before, until it acquires the temperature of the room.
What then, Dr. Black enquired, becomes of the heat which has been all
along given to the vessel of ice? Heat has been communicated to it as
well as to the other vessel; yet it has not been employed in raising the
temperature, but in some way has been expended in converting the ice
into water. It is but this simple fact otherwise stated, when we say
that the heat so imparted has _disappeared_ as heat of temperature; but
may it not have been destroyed or annihilated? To reply to this question
we have only to consider that the same vessel of water, cooled nearly to
the freezing point, and then exposed to a much greater degree of cold,
must, by the same rule, continue parting with its excess of temperature
above that of the colder bodies around it. Yet a thermometer immersed in
it continues invariably at 32° till the whole has become ice; it then
will sink to the lower temperature, but not before. Thus there must be
within it a continued supply of _heat_ in order to keep it up to 32° all
the time.
Public-domain text, read in full here on John Shaqi.
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