The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
The subdivision, produced by folding the loose page, is intended
to show that the elements represented on it have a double set of
resemblances. But there are various anomalous and inexplicable
phenomena still attached to this arrangement of elements. For example,
copper, although it replaces one atom of hydrogen in some of its
compounds, and is thus a monad, forms more numerous and more stable
compounds in acting as a dyad and replacing two atoms of hydrogen.
Gold, which belongs to the same column, is at once univalent and
tervalent; mercury, both univalent and bivalent; thallium, univalent
and tervalent; tin and lead, bivalent and quadrivalent, and so on. It
is as if some elements had a tendency to enter a column not their own.
Again, on comparing the atomic weights of the elements, it is seen that
the differences are far from being regular. As a rule, the difference
in the vertical columns between any single element and the one
following it is approximately 16, or some multiple of 16. Thus we have
lithium, sodium, and potassium; beryllium, magnesium, and calcium;
boron, aluminium, and scandium; carbon and silicon; oxygen and sulphur;
fluorine and chlorine--all with a difference of 16 approximately. But
here we come to a break: silicon and titanium, phosphorus and vanadium,
sulphur and chromium, chlorine and manganese, each show a difference of
about 20.
Passing on, between the atomic weights of potassium, rubidium, and
caesium there is a difference of about 16 × 3; a similar difference
between calcium, strontium, and barium; between scandium and yttrium;
between titanium, zirconium, and cerium, and so on; but with wider
and wider divergence from the supposed constant, 48 = 16 × 3. In
short, we have a seeming regularity, but only a very approximate
one--a regularity, in fact, in which a vivid imagination must play a
conspicuous part in order to detect it.
Now, up to the present, no reason has been suggested to account for the
divergence from this irregular regularity, which a little expenditure
of time will enable any one to trace through all these numbers. But one
thing has been remarked; there is the same seeming regularity between
certain physical properties of elements and their compounds: their
specific volumes, their melting-points, their refractive indices, and
other properties vary from member to member of the same column in a
manner bearing more or less similarity to the periodic variation of the
atomic weights.
It happens that among compounds of carbon we are acquainted with series
of compounds which, in variation of molecular weights and gradation of
properties, bear a striking resemblance to the elements thus arranged.
Thus we have the series:--
CH_{4} Methane 16
C_{2}H_{6} Ethane 30
C_{3}H_{8} Propane 44
C_{4}H_{10} Butane 58
C_{5}H_{12} Pentane 72
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