The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
Other evidence may be sought for in the spectrum of argon, which was
carefully examined by Mr. Crookes. It consists of a great number of
lines, extending all through the spectrum, from far down in the red to
far beyond the visible violet; the invisible lines were examined by
the aid of photography, for ultraviolet light, although invisible to
the eye, impresses a photographic plate. The most striking feature of
this spectrum is the change which can be produced in it by altering the
intensity of the electric discharge which is passed through the tube
containing argon at a low pressure. By interposing a Leyden jar between
the secondary terminals of the induction-coil from which sparks are
taken through the gas, the colour of the light in the tube changes from
a brilliant red to an equally brilliant blue. A large number of lines
in the red spectrum disappear, on interposing the jar, while many lines
in the blue-green, blue, and violet part of the spectrum, invisible
before, shine out with great brilliancy. There is no other gas in which
a similar alteration of intensity of discharge produces such a marked
difference, although in many gases, supposed to be simple substances,
similar changes may be produced. So far as we know at present, however,
such a change cannot be definitely ascribed to the presence of a
mixture of two elements, although it is in itself a very remarkable
phenomenon.
On the other hand, Professors Runge and Paschen, in a paper
communicated to the Royal Academy of Science of Berlin in July 1895,
have adduced reasons for concluding that helium, the gas from clèveite,
is a mixture; it appears to show lines belonging to two spectra, each
series of lines exhibiting certain regularities. But this, although an
important conclusion in itself, has no direct bearing on the question
of the simplicity of argon.
One method of separating the constituents of a mixture is by taking
advantage of their different solubilities in water, or in some other
appropriate solvent. And as argon was found to have the solubility of 4
volumes in 100 of water, while helium is very sparingly soluble, only
0·7 volume per 100, it is not unreasonable to suppose that, if argon
consisted of a mixture of elements in argon, one should be more soluble
than another. Exhaustive experiments in this direction have still to
be carried out; but Lord Rayleigh has made experiments which render it
very improbable that any separation into its constituents, if it be a
mixture, can be thus effected. Wishing to ascertain if there were any
helium in the air, he shook up atmospheric argon with water, until a
very small fraction remained undissolved. The spectrum of this small
residue was identical with that of the original argon, from which it
would appear that this method, at least, is incapable of effecting any
separation.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account