The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
“About eight days ago, I discovered that sulphur, when
burned, instead of losing weight, gains weight; that is
to say, from one pound of sulphur much more than one
pound of vitriolic acid is produced, not counting the
moisture gained from the air. Phosphorus presents the same
phenomenon. This increase of weight is due to a great
quantity of air which becomes fixed during the combustion,
and which combines with the vapours. This discovery, which
I confirmed by experiments which I regard as decisive,
led me to think that what is observed in the combustion
of sulphur and phosphorus might likewise take place with
respect to all the bodies which augment in weight by
combustion and calcination; and I was persuaded that the
gain of weight in calces of metals proceeded from the
same cause. Experiment fully confirmed my conjectures. I
effected the reduction of litharge in closed vessels with
Hales’ apparatus, and I observed that at the moment of the
passage of the calx into the metallic state, there was a
disengagement of air in considerable quantity, and that
this air formed a volume at least a thousand times greater
than that of the litharge employed. As this discovery
appears to me to be one of the most interesting which has
been made since the time of Stahl, I thought it expedient
to secure to myself the property, by depositing the present
note in the hands of the Secretary of the Academy, to
remain secret till the period when I shall publish my
experiments.”
LAVOISIER.
“PARIS, _11th November 1772_.”
[Illustration: ANTOINE AUGUSTE LAVOISIER.]
There is no account in Hales’ work of his reducing litharge in closed
vessels. It is to be presumed that Lavoisier heated in a retort a
mixture of litharge and charcoal, and that the air which he speaks of
was a mixture of oxides of carbon. This account does not inform us of
Lavoisier’s views on combustion, but merely shows the date at which he
had first obtained what he supposed were results new to science. We
recognise that Mayow had anticipated him in this.
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