The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
It was not until Priestley, when dining with him in the autumn of
1774 (being in Paris with Lord Shelburne at the time), had informed
Lavoisier of his discovery of “dephlogisticated” air, that the ideas
of the latter upon the subject became precise. Priestley’s own words
are:--“Having made the discovery some time before I was in Paris, in
the year 1774, I mentioned it at the table of Mr. Lavoisier, when most
of the philosophical people of the city were present, saying that it
was a kind of air in which a candle burned much better than in common
air, but I had not then given it any name. At this all the company,
and Mr. and Mrs. Lavoisier as much as any, expressed great surprise.
I told them I had gotten it from _precipitate per se_, and also
from _red-lead_. Speaking French very imperfectly, and being little
acquainted with the terms of chemistry, I said _plombe rouge_, which
was not understood till Mr. Macquer said I must mean _minium_.”
Shortly after this, Lavoisier repeated Priestley’s experiments and
confirmed their truth; and this led to the true explanation of
experiments of which an account is given in the _Memoirs_ of the French
Academy for 1774, and which were fundamental in their character. They
referred to the calcination of tin in hermetically-sealed retorts. The
tin was placed in a retort which was heated on a sand-bath until the
metal had melted. The beak of the retort, previously drawn out into a
capillary, was then sealed, the air expelled having been collected and
its weight noted. The retort was then cooled and weighed. It was again
heated, and the temperature was maintained until the calcination of the
tin stopped. With a large retort the calcination was more complete than
when a smaller one was employed, this implying that the degree to which
the calcination proceeded was dependent upon the amount of air present.
After cooling the retort a second time, it was again weighed, when it
was found to have undergone no change of weight. The beak was then
broken, and air entered with a hissing noise. The gain in weight was
now about 10 grains with a large retort. The tin and its calx were next
weighed, and it was found that the gain in weight of the tin was always
equal to the loss of weight of the air in the retort, measured by the
quantity of air which entered on breaking the beak of the retort, less
the air driven out of the retort before hermetically sealing it. From
this Lavoisier concluded that calx of tin is a compound of tin and air.
Public-domain text, read in full here on John Shaqi.
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