The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
The explanation of the solution of metals in acids was now easy:
it depended on the decomposition of water. While the oxygen united
with the metal to form a calx, the hydrogen was evolved; the calx
dissolved in the acid, forming a salt of the metal. And the operation
of producing hydrogen by the action of steam on red-hot iron met
with an equally simple explanation: the oxygen and iron united to
form an oxide--the ancient _ethiops martial_--while the hydrogen
escaped. The converse took place during the reduction of a calx to the
metallic state by hydrogen. Here the hydrogen seized on the oxygen of
the calx, removed it in the form of water, and the metal was left.
These experiments were due to Cavendish; all that Lavoisier did was
to show the true nature of the phenomena. The opponents of the new
doctrines, Priestley chief among them, did their best to disprove the
view that water was a compound of oxygen and hydrogen. But in vain.
Many of Lavoisier’s opponents had to admit the justice of his views;
and in 1787 De Morveau, Berthollet, and Fourcroy joined Lavoisier in
reconstructing the nomenclature of chemistry on a new basis, which
is substantially that in use at the present day. Black, too, was a
convert, but Priestley and Cavendish remained true to their old
faith, and one of Priestley’s last acts was to publish a defence of
the phlogistic theory. We shall see later how Cavendish carefully
considered the rival theories, and what reasons induced him to cast his
vote for the older one.
Among the numerous memoirs which Lavoisier communicated to the Academy
during the ten years between 1772 and 1782, one still remains to be
mentioned. It was published as early as 1777, but it must be remembered
that many of these memoirs were antedated. It referred to the
respiration of animals; and Lavoisier concluded, on the ground that the
phenomena of respiration are essentially similar to those of combustion
and calcination, that the only portion of the air which supports animal
life is the oxygen. The azote or nitrogen is inhaled along with the
oxygen, but is exhaled unaltered. The oxygen, however, is gradually
converted into carbonic acid; and when a certain amount, but by no
means the whole, has been thus changed, the air becomes unfit for
respiration. If the carbonic acid is withdrawn by means of lime-water
or caustic alkali, the residue is air poor in oxygen, and the azote is
the same as that left after the calcination of metals, or the burning
of a candle, in air.
At the time of his impeachment, Lavoisier was engaged in experiments
on perspiration, along with Séguin. He had nearly finished his
experimental work, but had drawn up no account of it. His request that
his life might be prolonged until he had compiled a statement of his
results was refused; but Séguin, who was fortunately spared, undertook
the task. The facts collected do not, however, bear directly on our
subject, and shall not be further alluded to here.
Public-domain text, read in full here on John Shaqi.
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