The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
This account of Lavoisier’s researches would be incomplete without
a reference to his text-book of chemistry, _Traité élémentaire de
Chimie_, in which his views are stated in order, and with great
clearness. The nomenclature current at the time was so cumbrous, that
it was almost, if not quite, impossible for the supporters of the new
theory to express their meaning in an intelligible manner. De Morveau
had suggested a nomenclature for salts; Black, too, had invented one;
but neither of these systems was adapted to represent the new views.
It was partly with the object of avoiding such embarrassment that
Lavoisier wrote his _Treatise_.
He begins with a clear statement of what is generally termed “the
states of matter”--solid, liquid, and gaseous--and points out
that solids and liquids are almost all capable of change into the
aeriform state by the addition of “caloric.” Proceeding next to the
consideration of the nature of air, he shows that it must necessarily
contain all those gases capable of existence at the ordinary
temperature; and he explains how water-vapour must be one of them,
seeing that even though water is a liquid at the ordinary temperature,
it is capable, like many other liquids, of existing as vapour, when
mixed with other gases. He next treats of the analysis of air, and
describes his classical experiment of heating four ounces of mercury
for twelve days in a retort communicating with a bell-shaped receiver,
standing in a mercury trough. Having marked the initial height of the
air in the jar by means of a piece of gummed paper, he found that,
after twelve days’ heating close to the boiling-point, the air had
diminished in volume by about one-sixth, and that the mercury had
become covered with a red deposit of _mercurius calcinatus per se_,
which, when collected, weighed 45 grains. The residual air in the
retort and in the jar was incapable of supporting life or combustion;
but the _red precipitate_, when heated, lost 3½ grains of its
weight, yielding 41½ grains of metallic mercury, while it evolved
7 or 8 cubic inches of oxygen, capable of supporting the combustion
of a candle vividly, and of causing charcoal to burn with a crackling
noise, throwing out sparks. Oxygen was thus successfully separated from
air, and obtained from it in a pure condition for the first time, in a
single series of operations.
Public-domain text, read in full here on John Shaqi.
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