The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
In determining the composition of the atmosphere, Cavendish made use of
nitric oxide in presence of water, as a means of removing oxygen. This
process, originally devised by Mayow, was rediscovered by Priestley,
who employed it to ascertain the “goodness” of various samples of
air; in Cavendish’s hands it became an accurate quantitative method.
The title of his paper, published in the _Philosophical Transactions_
for 1783, is “Of a new Eudiometer.” The term “eudiometer,” signifying
“measurer of goodness,” was devised when it was supposed that ordinary
air presented considerable variations in its power of supporting
respiration and combustion, according to the seasons, and according
to the place from which it was collected. Dr. Ingenhousz had found a
greater absorption when air from near the sea-coast was tested by
Priestley’s method with nitric oxide, than when town-air was employed;
and he ascribed the salubrious nature of sea-air to its being richer
in “vital air.” The Abbé Fontana, too, had made similar experiments,
and had come to similar conclusions. Cavendish modified Fontana’s
apparatus, rendering it capable of giving more accurate results; and
during the last half of the year 1781 he analysed the air collected on
sixty days, some fine, some wet, and some foggy. He also collected air
from different localities, sometimes at Marlborough Street, sometimes
at Kensington, which was then a country village. The results of his
analyses establish as the composition of air, freed from carbon dioxide
by potash:
79·16 per cent of phlogisticated air (nitrogen).
20·84 per cent of dephlogisticated air (oxygen).
This result does not differ materially from those obtained by the best
modern analyses, which give, within very small variations:
79·04 per cent of nitrogen and argon,
20·96 per cent of oxygen,
after absorption of carbon dioxide, ammonia, and water-vapour.
In the following year, 1784, Cavendish published the first of his great
memoirs, entitled _Experiments on Air_. His experiments were made
principally “with a view to find out the cause of the diminution which
common air is well known to suffer by all the various ways in which it
is phlogisticated, and to discover what becomes of the air thus lost or
condensed.”
Cavendish chose processes for “phlogisticating” air in the course of
which no fixed air should be produced. He therefore avoided the use of
animal and vegetable materials, and confined himself to combustibles,
such as sulphur or phosphorus, to the calcination of metals, the
explosion of inflammable air, and the mixture of nitrous air. He adds
as a suggestion, “Perhaps it may be supposed that I ought to add to
these the electric spark; but I think it much more likely that the
phlogistication of the air, and production of fixed air, in this
process is owing to the burning of some inflammable matter in the
apparatus.” We shall see later what magnificent results arose from this
last mode of “phlogisticating” air.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account