The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
He begins with an account of a repetition of an experiment of Mr.
Waltire’s, related by Priestley, in which a mixture of hydrogen and air
was exploded in a copper vessel, with the result that they observed
a loss of a few grains in weight; it is also stated by Waltire that
if the explosion took place in a glass vessel, it became dewy, “which
confirmed an opinion he had long entertained, that common air deposits
its moisture by phlogistication.” But Cavendish, using a glass vessel
of much greater capacity than Waltire’s, could remark no change of
weight; and he concluded that 423 measures of hydrogen, or “inflammable
air” as he named it, are “nearly sufficient to completely phlogisticate
1000 of common air, and that the bulk of the air remaining after the
explosion is then very little more than ⅘ths of the common air
employed; so that, as common air cannot be reduced to a much less bulk
than that, by any method of phlogistication, we may safely conclude
that, when they are mixed in this proportion and exploded, almost all
the inflammable air, and about ⅕th part of the common air, lose their
elasticity, and are condensed into the dew which lines the glass.
“The better to examine the nature of this ‘dew,’ 500,000 grain measures
of inflammable air were burnt with about 2½ times that quantity of
common air, and the burnt air made to pass through a glass cylinder 8
feet long and about ¾ of an inch in diameter, in order to deposit the
dew”. “By this means upwards of 135 grains of water were condensed in
the cylinder, which had no taste or smell, and which left no sensible
sediment when evaporated to dryness, neither did it yield any pungent
smell during the evaporation; in short, it seemed pure water”. “And
by this experiment it appears that this dew is plain water, and
consequently that almost all the inflammable and about ⅕th of the
common air are turned into pure water.”
But on firing little by little a mixture of “dephlogisticated air” or
oxygen, obtained from red precipitate (that is, mercuric oxide prepared
by heating the nitrate), with twice its volume of “inflammable air” or
hydrogen, the resulting water was acid to the taste, and on evaporation
with alkali gave a small quantity--about 2 grains--of nitre. Cavendish
suspected that the acid came from the nitrate of mercury in his
red precipitate, and, to test this, procured his oxygen from other
sources--from red-lead and sulphuric acid, and from the leaves of
plants--but still with the same result; nitric acid was formed.
Repeating the experiment so as to have present an excess of hydrogen,
he found that no acid was produced.
Public-domain text, read in full here on John Shaqi.
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