The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
It was not inconceivable that if such a “silent electric discharge”
were to be passed through “atmospheric” nitrogen, it might increase the
number of such three-atom molecules, and might render the gas still
denser; or if passed through “chemical” nitrogen, it might increase its
density so as to make it equal to that of “atmospheric” nitrogen. Lord
Rayleigh made such experiments, but without changing the density in the
least: the nitrogen from ammonia or from oxides of nitrogen, which has
been termed “chemical” nitrogen, still remained too light by about one
two-hundredth, and the atmospheric nitrogen still remained too heavy by
the same amount.
At this stage Professor Ramsay asked and received permission to make
some experiments on the nitrogen of the atmosphere, with the view of
explaining its anomalous behaviour. He had several years before made
experiments on the possibility of causing nitrogen and hydrogen to
combine directly, by passing the mixture over heated metals; among
these was magnesium, and although no direct combination to any great
extent was observed, still it was noticed that magnesium was a good
absorbent for nitrogen, when that gas was passed over the red-hot
filings of the metal. This process was therefore applied to the
absorption of “atmospheric” nitrogen, in order to find out whether any
portion of it was different from the rest. The plan adopted was to
heat turnings of magnesium, which can be made very thin and loose, to
redness in a tube of hard glass, in contact with the nitrogen of the
atmosphere, carefully purified from oxygen, which would otherwise have
also combined with the metallic magnesium. As absorption proceeded,
more nitrogen was admitted from a reservoir, and after a certain
quantity had been absorbed, the residual gas was extracted from the
tube by a mercury pump, and weighed.
The amount weighed was very small,--smaller perhaps than had up till
then been thought possible, if accurate results were to be obtained.
But here large differences were to be looked for. Only 40 cubic
centimetres--the twenty-fifth part of a litre--was weighed; and its
weight was only 0·050 gram. But with careful weighing the error should
not exceed one five-hundredth of the amount weighed; and if there were
to be any increase in density, that increase should be expected greatly
to exceed this small fraction.
The first weighing--in May 1894--showed that the nitrogen had increased
in density by reason of the operations, and instead of being fourteen
times as heavy as hydrogen, it was nearly fifteen times as heavy.
[Illustration: FIG. 1.]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account