The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
At this stage the two discoverers joined forces, and letters passed
almost daily between them, describing the results of experiments which
one or other had made. And just prior to the meeting of the British
Association at Oxford in August 1895, it was decided that the proof of
the existence of a new constituent gas in air was sufficiently clear to
render it advisable to make to the Association a short announcement of
the discovery. The statement was received with surprise and interest;
chemists were naturally somewhat incredulous that air, a substance of
which the composition had been so long and so carefully studied, should
yield anything new. One of the audience inquired whether the name of
this new substance had been discovered; as a matter of fact it was then
under consideration.
But it was still conceivable, although improbable, that the new gas was
being produced by the very processes designed for its separation, and
attention was first turned to devising a complete proof of its actual
presence in air. Now it is known that the rates of diffusion of gases
through a narrow opening, or through a number of minute holes, such
as exist in a pipe of porous clay, _e.g._ a tobacco-pipe stem, are in
inverse proportion to the square roots of the densities of the gases.
Oxygen is, in round numbers, sixteen times as dense as hydrogen; the
square roots of 16 and 1 being 4 and 1, it was found by Graham, who
first carefully investigated this subject, that four times as much
hydrogen would pass through a porous diaphragm, in a given time, as
oxygen. The _compound_ of hydrogen and oxygen, however, in the state
of gas, _viz._ steam, is not separated by such a process into its
constituents; it diffuses as such, and since it is nine times as dense
as hydrogen, the relative rates of diffusion of steam and hydrogen are
as 1: √9, or as 1 to 3; that is, for every 3 parts of hydrogen
passing through such a septum, 1 part of steam would pass in the same
time.
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