The Glaciers of the Alps: Being a narrative of excursions and ascents, an account of the origin and phenomena of glaciers and an exposition of the physical principles to which they are relatedTyndall, John
Science
The Glaciers of the Alps: Being a narrative of excursions and ascents, an account of the origin and phenomena of glaciers and an exposition of the physical principles to which they are related
Tyndall, John
Alps -- Description and travel; Glaciers -- Alps
When a liquid is heated, the attraction of the molecules operates
against the action of the heat, which tends to tear them asunder. At a
certain point the force of heat triumphs, the cohesion is overcome, and
the liquid boils. But supposing we assist the attraction of the
molecules by applying an external pressure, the difficulty of tearing
them asunder will be increased; more heat will be required for this
purpose; and hence we say that the _boiling point_ of the liquid has
been _elevated_ by the pressure.
[Sidenote: INFLUENCE OF PRESSURE ON FUSING POINT.]
If molten sulphur be poured into a bullet-mould, it will be found on
cooling to contract, so as to leave a large hollow space in the middle
of each sphere. Cast musket-bullets are thus always found to possess a
small cavity within them produced by the contraction of the lead.
Conceive the bullet placed within its mould and the latter heated; to
produce fusion it is necessary that the sulphur or the lead should
_swell_. Here, as in the case of the heated water, the tendency to
expand is opposed by the attraction of the molecules; with a certain
amount of heat however this attraction is overcome and the solid
_melts_. But suppose we assist the molecular attraction by a suitable
force applied externally, a greater amount of heat than before will be
necessary to tear them asunder; and hence we say that the _fusing
point_ has been _elevated_ by the pressure. This fact has been
experimentally established by Messrs. Hopkins and Fairbairn, who applied
to spermaceti and other substances pressures so great as to raise their
points of fusion a considerable number of degrees.
Let us now consider the case of the metal bismuth. If the molten metal
be poured into a bullet-mould it will _expand_ on solidifying. I have
myself filled a strong cast-iron bottle with the metal, and found its
expansion on cooling sufficiently great to split the bottle from neck to
bottom. Hence, in order to fuse the bismuth the substance must
_contract_; and it is manifest that an external pressure which tends to
squeeze the molecules more closely together here _assists_ the heat
instead of opposing it. Hence, to fuse bismuth under great pressure, a
less amount of heat will be required than when the pressure is removed;
or, in other words, the fusing point of bismuth is _lowered_ by the
pressure. Now, in passing from the solid to the liquid state, _ice_,
like bismuth, contracts, and if the contraction be promoted by external
pressure, as shown by the Messrs. Thomson, a less amount of heat
suffices to liquefy it.
[Sidenote: EXPERIMENTS.]
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