The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
The distillate passes into a row of condensers, to each of which is
attached a receptacle or receiver. It is needless to state that the
condensing capacity should be in excess of theoretical requirements. The
fractions are of varying strengths and quality; that portion, with a
density less than 14 deg. Tw. (19.4 deg. B.), is returned to the treated-lyes
tank. The other portion of the distillate is concentrated by means of a
dry steam coil in a suitable vessel under a 28 inch vacuum.
When sufficiently concentrated the glycerine may be decolorised, if
necessary, by treating with 1 per cent. animal charcoal and passing
through a filter press, from which it issues as "dynamite glycerine".
The residue in the still, consisting of 50-60 per cent. glycerine and
varying proportions of various sodium salts--_e.g._ acetate, chloride,
sulphate, and combinations with non-volatile organic acids--is generally
boiled with water and treated with acid.
The tar, which is separated, floats on the surface as the liquor is
cooling, and may be removed by ladles, or the whole mixed with waste
charcoal, and filtered.
The filtrate is then evaporated, when the volatile organic acids are
driven off; the concentrated liquor is finally mixed with crude
glycerine which is ready for distillation, or it may be distilled
separately.
_Distilled Glycerine._--This class of commercial glycerine, although of
limited use in various other branches of industry, finds its chief
outlet in the manufacture of explosives.
Specifications are usually given in contracts drawn up between buyers
and sellers, to which the product must conform.
The chief stipulation for dynamite glycerine is its behaviour in the
nitration test. When glycerine is gradually added to a cold mixture of
strong nitric and sulphuric acids, it is converted into nitro-glycerine,
which separates as an oily layer on the surface of the acid. The more
definite and rapid the separation, the more suitable is the glycerine
for dynamite-making.
Dynamite glycerine should be free from arsenic, lime, chlorides, and
fatty acids, the inorganic matter should not amount to more than 0.1 per
cent., and a portion diluted and treated with nitrate of silver solution
should give no turbidity or discoloration in ten minutes. The specific
gravity should be 1.262 at 15 deg. C. (59 deg. F.) and the colour somewhat
yellow.
_Chemically pure glycerine_ or double distilled glycerine is produced by
redistilling "once distilled" glycerine. Every care is taken to avoid
all fractions which do not withstand the nitrate of silver test. The
distillation is very carefully performed under strict supervision.
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