The handbook of soap manufactureSimmons, W. H. (William Herbert)
Science
The handbook of soap manufacture
Simmons, W. H. (William Herbert)
Soap
_Carapa_ or _Andiroba oil_, derived from the seeds of a tree (_Carapa
Guianensis_) grown in West Indies and tropical America, has been
suggested as suitable for soap-making. Deering (_Imperial Institute
Journ._, 1898, 313) gives the following figures:--
____________________________________________
| | | |
| Saponification | Acidity | Melting Point |
| Equivalent | Per Cent. | of Fatty |
| | | Acids, deg.C. |
|________________|___________|_______________|
| | | |
| 287 | 12 | 89 |
|________________|___________|_______________|
Another observer (_Rev. Chem. Ind._, 13, 116) gives the setting point of
the fatty acids as 56.4 deg. C.
_Candle-nut oil_ obtained from the seeds of a tree flourishing in India
and also the South Sea Islands.
The following figures have been published:--
_____________________________________________________________________________
| | | | |
| Saponi- | | | |
| fication | Titre,| Iodine No. | Observers.| References.
| Equiv- | | | |
| alent.[1] | deg.C.| | |
|___________|_______|____________|____________|_______________________________
| | | | |
| 299-304.9 | 13 | 136.3-139.3| De Negri |_Chem. Centr._, 1898, p. 493.
| 291 | | 163.7 | Lewkowitsch|_Chem. Revue_, 1901, p. 156.
| 296 | 12.5 | 152.8 | Kassler |_Farben-Zeitung_, 1903, p. 359.
|___________|_______|____________|____________|_______________________________
_Curcas oil_ is produced in Portugal from the seeds of the "purging nut
tree," which is similar to the castor oil plant, and is cultivated in
Cape Verde Islands and other Portuguese Colonies.
The following data have been observed:--
______________________________________________________________________________
| | | | |
| Saponi- | | | |
| fication | Titre,| Iodine No. | Observers.| References.
| Equiv- | | | |
| alent.[2] |deg.C. | | |
|___________|_______|____________|____________|_______________________________
| | | | |
| 291.4 | 0.36 | 99.5 | Archbut |_J. S. C. Ind._, 1898, p. 1010.
| 290.3 | 4.46 | 98.3 | Lewkowitsch|_Chem. Revue_, 1898, p. 211.
| 283.1 | 0.68 | 107.9 | Klein |_Zeits. angew. Chem._,
| | | | | 1898, p. 1012.
|___________|_______|____________|____________|_______________________________
The titre is quoted by Lewkowitsch as 28.6 deg. C.
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