The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
His paper on sympathetic ink is of more importance. A German chemist
had shown him a saline solution of a red colour which became blue when
heated: this led him to form a sympathetic ink, which was pale red,
while the paper was moist, but became blue upon drying it by holding it
to the fire. This sympathetic ink was a solution of cobalt in muriatic
acid. It does not appear from Hellot’s paper that he was exactly aware
of the chemical constitution of the liquid which constituted his
sympathetic ink; though it is clear he knew that cobalt constitutes an
essential part of it.
Kunkel’s phosphorus, though it had been originally discovered in
Germany, could not be prepared by any of the processes which had been
given to the public. Boyle had taught his operator, Godfrey Hankwitz,
the method of making it. This man had, after Boyle’s death, opened a
chemist’s shop in London, and it was he that supplied all Europe with
this curious article: on that account it was usually distinguished
by the name of _English phosphorus_. But in the year 1737 a stranger
appeared in Paris, who offered for a stipulated reward to communicate
the method of manufacturing this substance to the Academy of Sciences.
The offer was accepted by the French government, and a committee of
the academy, at the head of which was Hellot, was appointed to witness
the process, and ascertain all its steps. The process was repeated
with success; and Hellot drew up a minute detail of the whole, which
was inserted in the Memoirs of the Academy, for the year 1737. The
publication of this paper constitutes an era in the preparation of
phosphorus: it was henceforward in the power of every chemist to
prepare it for himself. A few years after the process was much improved
by Margraaf; and, within little more than twenty years after, the very
convenient process still in use was suggested by Scheele. Hellot’s
experiments on the comparative merits of the salts of Peyrac, and of
Pecais were of importance, because they decided a dispute--they may
also perhaps be considered as curiosities in an historical point of
view; because we see from them the methods which Hellot had recourse to
at that early period in order to determine the purity of common salt.
They are not entitled, however, to a more particular notice here.
In the year 1740 M. Hellot was charged with the general inspection of
dyeing; a situation which M. du Foy had held till the time of his death
in 1739. It was this appointment, doubtless, which turned his attention
to the theory of dyeing, which he tried to explain in two memoirs read
to the academy in 1740 and 1741. The subject was afterwards prosecuted
by him in subsequent memoirs which were published by the academy.
Public-domain text, read in full here on John Shaqi.
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