The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
Dr. Black’s writings are exceedingly few, consisting altogether of
no more than three papers. The first, entitled “Experiments upon
Magnesia alba, Quicklime, and other Alkaline Substances,” constituted
the subject of his inaugural dissertation. It afterwards appeared
in an English dress in one of the volumes of The Edinburgh Physical
and Literary Essays, in the year 1755. Mr. Creech, the bookseller,
published it in a separate pamphlet, together with Dr. Cullen’s
little essay on the “cold produced by evaporating fluids,” in the
year 1796. This essay exhibits one of the very finest examples of
inductive reasoning to be found in the English language. The author
shows that magnesia is a peculiar earthy body, possessed of properties
very different from lime. He gives the properties of lime in a pure
state, and proves that it differs from limestone merely by the absence
of the carbonic acid, which is a constituent of limestone. Limestone
is a _carbonate of lime_; quicklime is the pure uncombined earth. He
shows that magnesia has also the property of combining with carbonic
acid; that caustic potash, or soda, is merely these bodies in a pure
or isolated state; while the mild alkalies are combinations of these
bodies with carbonic acid. The reason why quicklime converts mild
into caustic alkali is, that the lime has a stronger affinity for
the carbonic acid than the alkali; hence the lime is converted into
carbonate of lime, and the alkali, deprived of its carbonic acid,
becomes caustic. Mild potash is a carbonate of potash; caustic potash,
is potash freed from carbonic acid.--The publication of this essay
occasioned a controversy in Germany, which was finally settled by
Jacquin and Lavoisier, who repeated Dr. Black’s experiments and showed
them to be correct.
Dr. Black’s second paper was published in the Philosophical
Transactions for 1775. It is entitled “The supposed Effect of boiling
on Water, in disposing it to freeze more readily, ascertained by
Experiments.” He shows, that when water that has been recently boiled
is exposed to cold air, it begins to freeze as soon as it reaches the
freezing point; while water that has not been boiled may be cooled some
degrees below the freezing point before it begins to congeal. But if
the unboiled water be constantly stirred during the whole time of its
exposure, it begins to freeze when cooled down to the freezing point as
well as the other. He shows that the difference between the two waters
consists in this, that the boiled water is constantly absorbing air,
which disturbs it, whereas the other water remains in a state of rest.
His last paper was “An Analysis of the Water of some boiling Springs
in Iceland,” published in the Transactions of the Royal Society of
Edinburgh. This was the water of the Geyser spring, brought from
Iceland by Sir J. Stanley. Dr. Black found it to contain a great deal
of silica, held in solution in the water by caustic soda.
Public-domain text, read in full here on John Shaqi.
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