The History of Chemistry, Volume 1 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 1 (of 2)
Thomson, Thomas
Chemistry -- History
3. Dr. Priestley, at a pretty early period of his chemical career,
had discovered that when nitrous gas is mixed with common air over
water, a diminution of bulk takes place; that there is a still greater
diminution of bulk when oxygen gas is employed instead of common
air; and that the diminution is always proportional to the quantity
of oxygen gas present in the gas mixed with the nitrous gas. This
discovery induced him to employ nitrous gas as a test of the quantity
of oxygen present in common air; and various instruments were contrived
to facilitate the mixture of the gases, and the measurement of the
diminution of volume which took place. As the goodness of air, or its
fitness to support combustion, and maintain animal life, was conceived
to depend upon the proportion of oxygen gas which it contained, these
instruments were distinguished by the name of _eudiometers_; the
simplest of them was contrived by Fontana, and is usually distinguished
by the name of the _eudiometer of Fontana_. Philosophers, in examining
air by means of this instrument, at various seasons, and in various
places, had found considerable differences in the diminution of
bulk: hence they inferred that the proportion of oxygen varies in
different places; and to this variation they ascribed the healthiness
or noxiousness of particular situations. For example, Dr. Ingenhousz
had found a greater proportion of oxygen in the air above the sea, and
on the sea-coast; and to this he ascribed the healthiness of maritime
situations. Mr. Cavendish examined this important point with his usual
patient industry and acute discernment, and published the result in the
Philosophical Transactions for 1783. He ascertained that the apparent
variations were owing to inaccuracies in making the experiment; and
that when the requisite precautions are taken, the proportion of oxygen
in air is found constant in all places, and at all seasons. This
conclusion has since been confirmed by numerous observations in every
part of the globe. Mr. Cavendish also analyzed common air, and found it
to consist of
79·16 volumes azotic gas,
20·84 volumes oxygen gas.
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100·00
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