The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
It was not till the year 1810, that the inaccuracy of these opinions
was established. Gay-Lussac and Thenard attempted in vain to
extract oxygen from chlorine. They showed that not a trace of that
principle could be detected. Next year Davy took up the subject and
concluded from his experiments that _chlorine_ is a simple substance,
that muriatic acid is a compound of chlorine and hydrogen, and
hyper-oxymuriatic acid of chlorine and oxygen. Gay-Lussac obtained this
acid in a separate state, and gave it the name of _chloric acid_, by
which it is now known.
Scheele, in his original experiments on chlorine, had noticed the
property which it has of destroying vegetable colours. Berthollet
examined this property with care, and found it so remarkable that
he proposed it as a substitute for exposure to the sun in bleaching.
This suggestion alone would have immortalized Berthollet had he done
nothing else; since its effect upon some of the most important of
the manufactures of Great Britain has been scarcely inferior to that
of the steam-engine itself. Mr. Watt happened to be in Paris when
the idea suggested itself to Berthollet. He not only communicated it
to Mr. Watt, but showed him the process in all its simplicity. It
consisted in nothing else than in steeping the cloth to be bleached
in water impregnated with chlorine gas. Mr. Watt, on his return to
Great Britain, prepared a quantity of this liquor, and sent it to his
father-in-law, Mr. Macgregor, who was a bleacher in the neighbourhood
of Glasgow. He employed it successfully, and thus was the first
individual who tried the new process of bleaching in Great Britain. For
a number of years the bleachers in Lancashire and the neighbourhood
of Glasgow were occupied in bringing the process to perfection. The
disagreeable smell of the chlorine was a great annoyance. This was
attempted to be got rid of by dissolving potash in the water to be
impregnated with chlorine; but it was found to injure considerably the
bleaching powers of the gas. The next method tried was to mix the water
with quicklime, and then to pass a current of chlorine through it. The
quicklime was dissolved, and the liquor thus constituted was found to
answer very well. The last improvement was to combine the chlorine
with dry lime. At first two atoms of lime were united to one atom of
chlorine; but of late years it is a compound of one atom of lime, and
one of chlorine. This chloride is simply dissolved in water, and the
cloth to be bleached is steeped in it. For all these improvements,
which have brought the method of bleaching by means of chlorine to
great simplicity and perfection, the bleachers are indebted to Knox,
Tennant, and Mackintosh, of Glasgow; by whose indefatigable exertions
the mode of manufacturing chloride of lime has been brought to a state
of perfection.
Public-domain text, read in full here on John Shaqi.
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