The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
I think it unnecessary to enter into any details respecting his
experiments on sulphuretted hydrogen, and the hydrosulphurets and
sulphurets. They contributed essentially to elucidate that obscure part
of chemistry. But his success was not perfect; nor did we understand
completely the nature of these compounds, till the nature of the
alkaline bases had been explained by the discoveries of Davy.
The only other work of Berthollet, which I think it necessary to notice
here, is his book entitled "Chemical Statics," which he published
in 1803. He had previously drawn up some interesting papers on the
subject, which were published in the Memoirs of the Institute. Though
chemical affinity constitutes confessedly the basis of the science,
it had been almost completely overlooked by Lavoisier, who had done
nothing more on the subject than drawn up some tables of affinity,
founded on very imperfect data. Morveau had attempted a more profound
investigation of the subject in the article _Affinité_, inserted in
the chemical part of the Encyclopédie Méthodique. His object was, in
imitation of Buffon, who had preceded him in the same investigation,
to prove that chemical affinity is merely a case of the _attraction of
gravitation_. But it is beyond our reach, in the present state of our
knowledge, to determine the amount of attraction which the atoms of
bodies exert with respect to each other. This was seen by Newton, and
also by Bergman, who satisfied themselves with considering it as an
attraction, without attempting to determine its amount; though Newton,
with his usual sagacity, was inclined, from the phenomena of light,
to consider the attraction of affinity as much stronger than that
of gravitation, or at least as increasing much more rapidly, as the
distances between the attracting particles diminished.
Bergman, who had paid great attention to the subject, considered
affinity as a certain determinate attraction, which the atoms of
different bodies exerted towards each other. This attraction varies
in intensity between every two bodies, though it is constant between
each pair. The consequence is, that these intensities may be denoted by
numbers. Thus, suppose a body _m_, and the atoms of six other bodies,
_a_, _b_, _c_, _d_, _e_, _f_, to have an affinity for _m_, the forces
by which they are attracted towards each other may be represented by
the numbers x, x+1, x+2, x+3, x+4, x+5. And the attractions may be
represented thus:
Attraction between _m_ & _a_ = x
_m_ & _b_ = x+1
_m_ & _c_ = x+2
_m_ & _d_ = x+3
_m_ & _e_ = x+4
_m_ & _f_ = x+5
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