The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
To analyze a mineral, or to separate it into its constituent parts, it
is necessary in the first place, to be able to dissolve it in an acid.
Bergman showed that most minerals become soluble in muriatic acid if
they be reduced to a very fine powder, and then heated to redness, or
fused with an alkaline carbonate. After obtaining a solution in this
way he pointed out methods by which the different constituents may be
separated one after another, and their relative quantities determined.
The fusion with an alkaline carbonate required a strong red heat.
An earthenware crucible could not be employed, because at a fusing
temperature it would be corroded by the alkaline carbonate, and thus
the mineral under analysis would be contaminated by the addition of a
quantity of foreign matter. Bergman employed an iron crucible. This
effectually prevented the addition of any earthy matter. But at a red
heat the iron crucible itself is apt to be corroded by the action of
the alkali, and thus the mineral under analysis becomes contaminated
with a quantity of that metal. This iron might easily be separated
again by known methods, and would therefore be of comparatively small
consequence, provided we were sure that the mineral under examination
contained no iron; but when that happens (and it is a very frequent
occurrence), an error is occasioned which we cannot obviate. Klaproth
made a vast improvement in the art of analysis, by substituting
crucibles of fine silver for the iron crucibles of Bergman. The only
difficulty attending their use was, that they were apt to melt unless
great caution was used in heating them. Dr. Wollaston introduced
crucibles of platinum about the beginning of the present century. It
is from that period that we may date the commencement of accurate
analyzing.
Bergman's processes, as might have been expected, were rude and
imperfect. It was Klaproth who first systematized chemical analysis and
brought the art to such a state, that the processes followed could
be imitated by others with nearly the same results, thus offering a
guarantee for the accuracy of the process.
Public-domain text, read in full here on John Shaqi.
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