The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
The red lead ore of Siberia had early drawn the attention of chemists,
on account of its beauty; and various attempts had been made to analyze
it. Among others, Vauquelin tried his skill upon it, in 1789, in
concert with M. Macquart, who had brought specimens of it from Siberia;
but at that time he did not succeed in determining the nature of the
acid with which the oxide of lead was combined in it. He examined
it again in 1797, and now succeeded in separating an acid to which,
from the beautiful coloured salts which it forms, he gave the name of
_chromic_. He determined the properties of this acid, and showed that
its basis was a new metal to which he gave the name of _chromium_. He
succeeded in obtaining this metal in a separate state, and showed that
its protoxide is an exceedingly beautiful green powder. This discovery
has been of very great importance to different branches of manufacture
in this country. The green oxide is used pretty extensively in painting
green on porcelain. It constitutes an exceedingly beautiful green
pigment, very permanent, and easily applied. The chromic acid, when
combined with oxide of lead, forms either a yellow or an orange colour
upon cotton cloth, both very fixed and exceedingly beautiful colours.
In that way it is extensively used by the calico-printers; and the
bichromate of potash is prepared, in a crystalline form, to a very
considerable amount, both in Glasgow and Lancashire, and doubtless in
other places.
Vauquelin was requested by Hauy to analyze the _beryl_, a beautiful
light-green mineral, crystallized in six-sided prisms, which occurs
not unfrequently in granite rocks, especially in Siberia. He found it
to consist chiefly of silica, united to alumina, and to another earthy
body, very like alumina in many of its properties, but differing in
others. To this new earth he gave the name of _glucina_, on account
of the sweet taste of its salts; a name not very appropriate, as
alumina, yttria, lead, protoxide of chromium, and even protoxide of
iron, form salts which are distinguished by a sweet taste likewise.
This discovery of glucina confers honour on Vauquelin, as it shows
the care with which his analyses must have been conducted. A careless
experimenter might easily have confounded _glucina_ with _alumina_.
Vauquelin's mode of distinguishing them was, to add sulphate of potash
to their solution in sulphuric acid. If the earth in solution was
alumina, crystals of alum would form in the course of a short time; but
if the earth was glucina, no such crystals would make their appearance,
alumina being the basis of alum, and not glucina. He showed, too, that
glucina is easily dissolved in a solution of carbonate of ammonia,
while alumina is not sensibly taken up by that solution.
Public-domain text, read in full here on John Shaqi.
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