The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
The importance of this instrument struck Bergman, and induced him
to wish for a complete examination of the action of the heat of the
blowpipe upon all different minerals, either tried _per se_ upon
charcoal, or mixed with various fluxes; for three different substances
had been chosen as fluxes, namely, _carbonate of soda_, _borax_, and
_biphosphate of soda_; or, at least, what was in fact an equivalent
for this last substance, _ammonio-phosphate of soda_, or _microcosmic
salt_, at that time extracted from urine. This salt is a compound
of one integrant particle of phosphate of soda, and one integrant
particle of phosphate of ammonia. When heated before the blowpipe it
fuses, and the water of crystallization, together with the ammonia, are
gradually dissipated, so that at last nothing remains but biphosphate
of soda. These fluxes have been found to act with considerable energy
on most minerals. The carbonate of soda readily fuses with those that
contain much silica, while the borax and biphosphate of soda act most
powerfully on the bases, not sensibly affecting the silica, which
remains unaltered in the fused bead. A mixture of borax and carbonate
of soda upon charcoal in general enables us to reduce the metallic
oxides to the state of metals, provided we understand the way of
applying the flame properly. Bergman employed Gahn, who was at that
time his pupil, and whose skill he was well acquainted with, to make
the requisite experiments. The result of these experiments was drawn
up into a paper, which Bergman sent to Baron Born in 1777, and they
were published by him at Vienna in 1779. This valuable publication
threw a new light upon the application of the blowpipe to the assaying
of minerals; and for every thing new which it contained Bergman was
indebted to Gahn, who had made the experiments.
Public-domain text, read in full here on John Shaqi.
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