The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
It was his celebrated paper "On some chemical Agencies of Electricity,"
inserted in the Philosophical Transactions for 1807, that laid the
foundation of the high reputation which he so deservedly acquired. I
consider this paper not merely as the best of all his own productions,
but as the finest and completest specimen of inductive reasoning
which appeared during the age in which he lived. It had been already
observed, that when two platinum wires from the two poles of a galvanic
pile are plunged each into a vessel of water, and the two vessels
united by means of wet asbestos, or any other conducting substance,
an _acid_ appeared round the positive wire and an _alkali_ round the
negative wire. The alkali was said by some to be _soda_, by others
to be _ammonia_. The acid was variously stated to be _nitric acid_,
_muriatic acid_, or even _chlorine_. Davy demonstrated, by decisive
experiments, that in all cases the acid and alkali are derived from
the decomposition of some salt contained either in the water or in
the vessel containing the water. Most commonly the salt decomposed
is common salt, because it exists in water and in agate, basalt, and
various other stony bodies, which he employed as vessels. When the same
agate cup was used in successive experiments, the quantity of acid
and alkali evolved diminished each time, and at last no appreciable
quantity could be perceived. When glass vessels were used, soda was
disengaged at the expense of the glass, which was sensibly corroded.
When the water into which the wires were dipped was perfectly pure,
and when the vessel containing it was free from every trace of saline
matter, no acid or alkali made its appearance, and nothing was evolved
except the constituents of water, namely, oxygen and hydrogen; the
oxygen appearing round the positive wire, and the hydrogen round the
negative wire.
When a salt was put into the vessel in which the positive wire dipped,
the vessel into which the negative wire dipped being filled with
pure water, and the two vessels being united by means of a slip of
moistened asbestos, the acid of the salt made its appearance round the
positive wire, and the alkali round the negative wire, before it could
be detected in the intermediate space; but if an intermediate vessel,
containing a substance for which the alkali has a strong affinity, be
placed between these two vessels, the whole being united by means of
slips of asbestos, then great part, or even the whole of the alkali,
was stopped in this intermediate vessel. Thus, if the salt was nitrate
of barytes, and sulphuric acid was placed in the intermediate vessel,
much sulphate of barytes was deposited in the intermediate vessel, and
very little or even no barytes made its appearance round the negative
wire. Upon this subject a most minute, extensive, and satisfactory
series of experiments was made by Davy, leaving no doubt whatever of
the accuracy of the fact.
Public-domain text, read in full here on John Shaqi.
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